54844-24-5

Upstream product

• 1516-28-5 allyl (p-tolyl)sulfide 
• 702-00-1 (2-methylallyl)(phenyl)sulfane 
• 106-45-6 para-thiocresol 
• 563-47-3 3-Chloro-2-methylpropene 
• 18292-38-1 2-methallyltrimethylsilane 
• 565184-53-4 1-(2-methoxy-2-methyl-pent-4-enylsulfanyl)-4-methyl-benzene 
• 103-19-5 di(p-tolyl) disulfide 
• 513-42-8 3-hydroxy-2-methyl-1-propene 

Downstream Products

• 54844-22-3 3-(p-tolylthio)-2-methyl-1-propanol 
• 74203-21-7 3-(p-tolylthio)-2-methyl-1-iodopropane 
• 78498-58-5 3-(p-Tolylthio)-2-methyl-1-aminopropane 
• 16192-04-4 1-methyl-4-(2-methylallylsulfonyl)benzene 
• 37616-05-0 1-methyl-4-((2-methylallyl)sulfinyl)benzene 

Relevant academic research and scientific papers

Coupling reaction of magnesium alkylidene carbenoids with α-sulfonylallyllithiums: An efficient route to multi-substituted vinylallenes

A variety of vinylallenes were successfully synthesized from 1-chlorovinyl p-tolyl sulfoxides and allyl or vinyl sulfones. Allyl and vinyl sulfones served as α-sulfonylallyllithium sources were prepared from carbonyl compounds in three or four steps in good overall yields. The coupling reaction of α-sulfonylallyllithiums with magnesium alkylidene carbenoids, which were generated from 1-chlorovinyl p-tolyl sulfoxides and isopropylmagnesium chloride, afforded multi-substituted vinylallenes in up to 88% yield. Georg Thieme Verlag KG Stuttgart · New York.

β-arylthio-α-chloroalkyl ethers - Novel 1,1-bis-electrophiles for geminal alkylation

A novel protocol for geminal alkylation is suggested based upon the consecutive generation of two cationoid intermediates from the easily prepared adducts of arylsulfenyl chlorides and vinyl ethers. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.