74228-25-4Relevant academic research and scientific papers
Fused ring non-fullerene acceptors with benzothiophene dioxide end groups and their side chain effect investigations
Deng, Min,Li, Ruipeng,Peng, Qiang,Xu, Xiaopeng,Yu, Liyang
, (2020/04/23)
The development of small molecule-based non-fullerene acceptors (NF-SMAs) greatly advanced the performances of polymer solar cells (PSCs) in recent years. As the foreseeability of commercializing this technology in the future, interest in reducing the materials cost is rising. To this end, efforts have been made in this work on exploring the usage of commercially available chemical segment of benzothiophene dioxide (BC) in constructing efficient NF-SMAs. Thus, we designed and synthesized two BC-based NF-SMAs, which showed high power conversion efficiency (PCE) of 7.59% also by device engineering and side chain engineering. Our work revealed the full potential of using BC end groups in constructing high-performance NF-SMAs and demonstrated the application of side chain engineering in tuning material properties and performances.
Preparation method of disperse blue 354
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Paragraph 0012; 0055-0056; 0068-0070; 0072-0074, (2019/02/06)
The invention relates to a preparation method of disperse blue 354. The preparation method is characterized by comprising the following steps: preparing a compound Ib, wherein methanol is used as a solvent, with the existence of pyridine, a compound Ia reacts with malononitrile in a mass ratio of 1: (0.4 to 0.5), and the reaction temperature is 45 DEG C to a reflux temperature of the methanol. Byadopting the preparation method, the consumption of malononitrile can be reduced, the reaction condition is mild, harmful substances can be reduced, and a product is good in purity and high in yield.The preparation method is low in initial raw material cost, and high in total yield.
Fused-ring non-fullerene receptor material and preparation method thereof and organic solar battery
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Paragraph 0084; 0100-0103; 0171; 0186-0188, (2019/02/04)
The invention relates to a fused-ring non-fullerene receptor material and a preparation method thereof and an organic solar battery. The fused-ring non-fullerene receptor material adopts a structuralgeneral formula as shown in the specification, wherein R
Sulfonyl-based non-fullerene electron acceptor-assisted grain boundary passivation for efficient and stable perovskite solar cells
Song, Changjian,Li, Xiaodong,Wang, Yueming,Fu, Sheng,Wan, Li,Liu, Shiyu,Zhang, Wenjun,Song, Weijie,Fang, Junfeng
supporting information, p. 19881 - 19888 (2019/09/07)
Passivating the grain boundary (GB) defects of polycrystalline perovskite films via fused-ring non-fullerene Lewis base deactivators is an effective approach to fabricate high-efficiency and high-stability perovskite solar cells (PSCs). We first introduce
Method for preparing disperse blue 354
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Paragraph 0013; 0036; 0041; 0046; 0051; 0056; 0061, (2017/08/28)
The invention discloses a method for preparing disperse blue 354. The method comprises the following steps: using dichloroethane as a reaction solvent, carbonyl iron powder as a catalyst, 3(2H)-indanone sulfur-1,1-dioxide and malononitrile as reaction raw materials, and obtaining an intermediate nitrile compound through a cyanation reaction; putting acetic acid, the intermediate nitrile compound, 2-methyl-4-aminobenzaldehyde and phosphoric acid into a reaction container to be stirred uniformly, then adding aluminum trichloride, putting bromohexane into a reaction system of a condensation section through a condensation reaction, and thus obtaining a target product through an alkylation reaction. A raw material 4-(N,N-dihexyl amino)-2-tolyl aldehyde is replaced with the 2-methyl-4-aminobenzaldehyde and the bromohexane; although one reaction is added, the added alkylation reaction and the condensation reaction are in the same system, and the operation difficulty coefficient is not added additionally; more importantly, the change of the technology promotes the process of the reaction to be more thorough, the yield of the product is further improved, and the total yield is 84% or more than 84%; and more importantly, industrialization is easy to realize, and the unit consumption of the product is reduced.
