74243-90-6

Upstream product

• 86990-89-8 (2S,3S)-4-(benzyloxy)-2-methylbutane-1,3-diol 
• 74213-62-0 diethyl (2S,3R)-erythro-3-methylmalate THP ether 
• 79246-57-4 (-)-(1'S,4S)-2,2-Dimethyl-4-(1-methyl-2-propenyl)-1,3-dioxolan 
• 74213-63-1 (2S,3S)-erythro-3-methylbutane-1,2,4-triol 2-THP ether 
• 73840-71-8 diethyl (2S,3R)-(+)-2-hydroxy-3-methylsuccinate 
• 95532-11-9 (2S,3S)-1,4-bis(benzyloxy)-3-methylbutan-2-ol 
• 74213-64-2 (2S,3S)-erythro-3-methylbutane-1,2,4-triol 
• 74243-88-2 (βS,4S)-β,2,3-trimethyl-1,3-dioxolane-4-ethanol 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 1417908-57-6 C₁₅H₂₂O₄S 
• 95532-21-1 (2R,3S,6R)-6-<(1S)-2-(benzyloxy)-1-methylethyl>tetrahydro-3-methyl-2H-pyran-2-carboxaldehyde 
• 81444-68-0 [(2R,3S,6R)-6-((S)-2-Benzyloxy-1-methyl-ethyl)-3-methyl-tetrahydro-pyran-2-yl]-methanol 
• 80109-44-0 (2S,3R,6S,7S)-4-(benzyloxy)-7,8-epoxy-2,6-dimethyl-3-octanol 
• 95588-33-3 (E)-(2S,3R,6S)-1-Benzyloxy-2-methyl-6-oxiranyl-hept-4-en-3-ol 
• 95532-20-0 (Z)-(2S,3R,6S)-1-Benzyloxy-2-methyl-6-(S)-oxiranyl-hept-4-en-3-ol 
• 95532-16-4 <(2R)-2-<(4S)-2,2-dimethyl-1,3-dioxolan-4-yl>propyl>triphenylphoshonium iodide 
• 80109-43-9 <<(1R,2Z/2E,4S)-1-<(1S)-2-(benzyloxy)-1-methylethyl>-4-<(4S)-2,2-dimethyl-1,3-dioxolan-4-yl>-2-pentenyl>oxy>-tert-butyldiphenylsilane 

Relevant academic research and scientific papers

Formal total synthesis of (-)-5,6-dihydrocineromycine B

An efficient and highly convergent formal total synthesis of the 14-membered macrolide (-)-5,6-dihydrocineromycine B is achieved. Key reaction sequences include a Sharpless asymmetric epoxidation followed by esterification for the formation of a fully functionalized acyclic precursor, Corey-Bakshi-Shibata reduction, and ring-closing metathesis, respectively. Georg Thieme Verlag KG Stuttgart · New York.

Total Synthesis of Ionophore Antibiotic X-14547A

A highly stereocontrolled and convergent total synthesis of optically active ionophore antibiotic X-14547A (1) was designed and carried out.Degradative reactions led to the key intermediates 3 and 6, which served as convenient comparison stages.The tetrah

Stereoselective synthesis of optically active forms of δ-multistriatin, the attractant for european populations of the smaller european elm bark beet

A stereoselective synthesis of highly optically pure enantiomers of δ-multistriatin [(1S,2S,4S,5R)-2,4-dimethyl-5-ethyl-6, 8-dioxabicyclo[3.2.1)octane and its antipode] was accomplished starting from tartaric acid enantiomers.