74260-32-5Relevant articles and documents
Synthesis of Benzyltributylstannanes by the Reaction of N-Tosylhydrazones with Bu3SnH
Qiu, Di,Wang, Shuai,Meng, He,Tang, Shengbo,Zhang, Yan,Wang, Jianbo
, p. 624 - 632 (2017/04/26)
An efficient stannylation process with N-tosylhydrazones or directly with carbonyl compounds has been developed. A series of functionalized benzyl- and alkyltributylstannanes can be synthesized in moderate to good yields under transition-metal-free conditions. Tandem transformations involving stannylation/Stille cross-coupling reaction have been carried out without purification of the benzyltributylstannane intermediates to afford a series of diarylmethane derivatives.
Silver(i)-promoted insertion into X-H (X = Si, Sn, and Ge) bonds with N-nosylhydrazones
Liu, Zhaohong,Li, Qiangqiang,Yang, Yang,Bi, Xihe
supporting information, p. 2503 - 2506 (2017/03/08)
Silver(i)-promoted carbene insertion into X-H (X = Si, Sn, and Ge) bonds has been realized by using unstable diazo compounds, which are generated in situ from N-nosylhydrazones as carbene precursors. The reaction tolerates a wide range of functional groups and delivers a number of valuable silicon-containing compounds in very high yields (up to 96%). Moreover, organostannanes and organogermanes were as well effectively obtained in very good yields under optimal conditions.
