74275-85-7

Downstream Products

• 1088991-30-3 C₂₀H₁₉ClO₂S 
• 1088991-29-0 C₂₀H₁₉ClO₂S 
• 1403964-80-6 C₁₂H₁₅OS⁽¹⁺⁾*C₁₃H₁₇F₂O₆S^(1-) 
• 1403964-79-3 C₁₂H₁₅OS⁽¹⁺⁾*C₁₇H₂₅F₂O₇S^(1-) 
• 1402933-09-8 C₁₂H₁₅OS⁽¹⁺⁾*C₁₃H₁₇F₂O₆S^(1-) 
• 1402933-08-7 C₁₂H₁₅OS⁽¹⁺⁾*C₁₃H₁₅F₂O₆S^(1-) 
• 1328506-34-8 C₅H₃F₂N₂O₄S^(1-)*C₁₂H₁₅OS⁽¹⁺⁾ 
• 1307627-88-8 C₁₂H₁₅OS⁽¹⁺⁾*C₁₃H₁₇F₂O₆S^(1-) 
• 1264173-48-9 C₂HF₂O₅S^(1-)*C₁₂H₁₅OS⁽¹⁺⁾ 

Relevant academic research and scientific papers

Reactions of group IV organometallic compounds XXV. Preparations and reactions of tetramethylene-[(α-trimethylsilyl- or α-trimethylstannyl)phenacyl]sulphonium salts and ylides

Tetramethylene[(α-trimethylsilyl- and α-trimethylstannyl)phenacyl]sulphonium salts [(CH2)4S+CH(MMe3)COPh]Cl- (M = Si and Sn) have been prepared by the reaction of tetramethylenesulphonium phenacyclide (I) with the relevant Me3MCl. The thermal rearrangement of tetramethylene[(α-trimethylsilyl)phenacyl]sulphonium chloride (II) unexpectedly afforded Cl(CH2)4SCHC(OSiMe3)Ph (III) by a 1,3-migration of the trimethylsilyl group to the oxygen atom accompanied by simultaneous ring-opening. Tetramethylene[(α-trimethylstannyl)phenacyl]sulphonium chloride (IV) gave the corresponding ylide (VI) by reaction with n-butyllithium.