7429-09-6Relevant academic research and scientific papers
Stereochemistry and Mechanism of Hydride Abstraction from Organostannanes
Hannon, S.J.,Traylor, T.G.
, p. 3645 - 3650 (1981)
The reaction of trityl cation with threo-3-deuterio-2-(trimethylstannyl)butane to produce 2-butenes was shown to proceed with about 99percent anti stereochemistry.The primary and secondary isotope effects are 3.7 and 1.1, respectively.These data are interpreted in terms of a hydride-abstraction mechanism leading to a ?-?-conjugated carbocation which subsequently loses the trimethyltin group.
