74320-39-1

Basic information

• Product Name: 3-Cyclohexene-1-carboxylic acid, 6-[2-(dimethylamino)-2-oxoethyl]-, methyl ester, cis-
• CAS NO: 74320-39-1
• Molecular Formula: C12H19NO3
• Molecular Weight: 225.288
• Mol File: 74320-39-1.mol

Chemical Properties

• CAS DataBase Reference: 3-Cyclohexene-1-carboxylic acid, 6-[2-(dimethylamino)-2-oxoethyl]-, methyl ester, cis-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Cyclohexene-1-carboxylic acid, 6-[2-(dimethylamino)-2-oxoethyl]-, methyl ester, cis-(74320-39-1)
• EPA Substance Registry System: 3-Cyclohexene-1-carboxylic acid, 6-[2-(dimethylamino)-2-oxoethyl]-, methyl ester, cis-(74320-39-1)

Safety Data

• Hazardous Substances Data: 74320-39-1(Hazardous Substances Data)

Upstream product

• 93531-06-7 (1S,6R)-6-Chlorocarbonyl-cyclohex-3-enecarboxylic acid methyl ester 
• 93603-11-3 1-methyl hydrogen 1,2-cis-1,2-cyclohex-4-ene dicarboxylate 
• 74207-04-8 methyl cis-6-<(diazomethyl)carbonyl>-3-cyclohexene-1-carboxylate 
• 124-40-3 dimethyl amine 

Downstream Products

• 116217-03-9 (3R,3aS,4R,7aS)-4-Benzyloxymethyl-3-methyl-3a,4,5,7a-tetrahydro-3H-benzofuran-2-one 
• 116217-03-9 (3S,3aS,4R,7aS)-4-Benzyloxymethyl-3-methyl-3a,4,5,7a-tetrahydro-3H-benzofuran-2-one 
• 116217-14-2 2,2-Dimethyl-propionic acid (S)-2-((1S,2S,3S,4S,6S)-4-benzyloxymethyl-2-methoxy-8-oxo-7-phenylsulfanyl-bicyclo[4.2.0]oct-3-yl)-propyl ester 
• 122131-25-3 2,2-Dimethyl-propionic acid (S)-2-((1R,2S,3S,4S,6S)-4-benzyloxymethyl-8-hydroxy-2-methoxy-7-phenylsulfanyl-bicyclo[4.2.0]oct-3-yl)-propyl ester 
• 116217-16-4 C₂₆H₃₆O₆ 
• 122131-34-4 C₂₆H₃₈O₆ 
• 116217-13-1 2,2-Dimethyl-propionic acid (S)-2-((1S,2S,3S,4S,6S)-4-benzyloxymethyl-7-chloro-2-methoxy-8-oxo-bicyclo[4.2.0]oct-3-yl)-propyl ester 
• 122131-35-5 C₂₄H₃₆O₅ 
• 122131-36-6 Acetic acid (R)-4-((1S,2R,3S,4S,6S)-4-benzyloxymethyl-2-methoxy-7-oxo-bicyclo[4.2.0]oct-3-yl)-pentyl ester 
• 116217-15-3 (S)-2-((1S,2S,3S,4S,6S)-4-Benzyloxymethyl-2-methoxy-7-phenylsulfanyl-bicyclo[4.2.0]oct-7-en-3-yl)-propan-1-ol 
• 116217-09-5 2,2-Dimethyl-propionic acid (S)-2-((1S,2R,6S)-6-benzyloxymethyl-2-methoxy-cyclohex-3-enyl)-propyl ester 
• 122131-33-3 C₂₂H₃₀O₅ 
• 122131-32-2 C₂₂H₃₂O₅ 
• 122131-30-0 2,2-Dimethyl-propionic acid (R)-2-((1R,2S,6R)-6-benzyloxymethyl-2-hydroxy-cyclohex-3-enyl)-propyl ester 

Relevant articles and documents

A Formal Total Synthesis of (+/-)-Vernolepin and (+/-)-Vernomenin

A formal total synthesis of (+/-)-vernolepin (1) and (+/-)-vernomenin (2) has been achieved starting from cis-4-cyclohexene-1,2-dicarboxylic acid monomethyl ester (5) via a novel intramolecular alkylation of 14 -> 16.The penultimate target was directed to