74357-22-5

Basic information

• Product Name: methyl-6-ethoxynicotinate
• Synonyms: methyl-6-ethoxynicotinate
• CAS NO: 74357-22-5
• Molecular Weight: 181.191
• Mol File: 74357-22-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl-6-ethoxynicotinate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl-6-ethoxynicotinate(74357-22-5)
• EPA Substance Registry System: methyl-6-ethoxynicotinate(74357-22-5)

Safety Data

• Hazardous Substances Data: 74357-22-5(Hazardous Substances Data)

Upstream product

• 93-60-7 methyl 3-pyridinecarboxylate 
• 64-17-5 ethanol 

Downstream Products

• 694-85-9 1-methyl-2-pyridone 
• 6375-89-9 methyl 1-methyl-6-oxo-1,6-dihydropyridine-3-carboxylate 
• 10561-91-8 ethyl 1-methyl-6-oxo-1,6-dihydropyridine-3-carboxylate 
• 24903-82-0 Ethyl-1-ethyl-1,6-dihydro-6-oxopyridin-3-carboxylat 
• 74925-38-5 methyl 1-ethyl-6-oxo-1,6-dihydropyridine-3-carboxylate 
• 13337-79-6 1-ethyl-2-pyridone 

Relevant articles and documents

MULTIPLE PATHS FOR PHOTOALKYLATION OF PYRIDINECARBOXYLIC ESTERS IN ALCOHOLS

Photochemical substitution of ring hydrogen of pyridinecarboxylic esters by alkyl groups derived from solvent alcohols occurs in several paths: 1) alkylation initiated by excited carbonyl moiety of the ester group and 2) alkylation initiated by the excitation of the ?-electronic system of the pyridine ring.In the photoreaction of methyl 3-pyridinecarboxylate in acidic methanol, three types of excited state (two triplet states for alkylation and a singlet state for alkoxylation) contribute simultaneously.