74386-28-0Relevant academic research and scientific papers
NEW TRANSFORMATIONS OF o-SUBSTITUTED AZOXYBENZENES
Mochalov, S. S.,Fedotov, A. N.,Kupriyanova, E. A.,Shabarov, Yu. S.
, p. 559 - 564 (2007/10/02)
Under the influence of equimolar amounts of bases, o-propionylazoxybenzenes undergo previously unknown transformations to difficult-to-obtain cinnolinones, bisindoxyls, and indolinones.The rations of the resulting transformation products depend on the substituent in the para position with respect to the propionyl group.Possible pathways for the transformations of monopropionylazoxybenzenes are discussed.
NEW REARRANGEMENT OF AZOXYBENZENES UNDER THE INFLUENCE OF CONCENTRATED SULFURIC ACID
Mochalov, S. S.,Fedotov, A. N.,Plotkin, V. Yu.,Shabarov, Yu. S.
, p. 534 - 541 (2007/10/02)
Under the influence of concentrated sulfuric acid 2-cyclopropylazoxybenzenes undergo rearrangement to acylated azobenzenes.In the case of 2,2'-dicyclopropylazoxybenzene nucleophilic assistance from the azoxy group is realized in the opening of the three-m
