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744202-15-1

Ni[bis(2-diphenylphosphinoethyl)phenylphosphine](2,4,6-trimercaptotriazine dianion) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 744202-15-1 Structure

  • Basic information

    1. Product Name: Ni[bis(2-diphenylphosphinoethyl)phenylphosphine](2,4,6-trimercaptotriazine dianion)
    2. Synonyms:
    3. CAS NO:744202-15-1
    4. Molecular Formula:
    5. Molecular Weight: 768.506
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 744202-15-1.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Ni[bis(2-diphenylphosphinoethyl)phenylphosphine](2,4,6-trimercaptotriazine dianion)(CAS DataBase Reference)
    10. NIST Chemistry Reference: Ni[bis(2-diphenylphosphinoethyl)phenylphosphine](2,4,6-trimercaptotriazine dianion)(744202-15-1)
    11. EPA Substance Registry System: Ni[bis(2-diphenylphosphinoethyl)phenylphosphine](2,4,6-trimercaptotriazine dianion)(744202-15-1)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 744202-15-1(Hazardous Substances Data)

744202-15-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 744202-15-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 7,4,4,2,0 and 2 respectively; the second part has 2 digits, 1 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 744202-15:
(8*7)+(7*4)+(6*4)+(5*2)+(4*0)+(3*2)+(2*1)+(1*5)=131
131 % 10 = 1
So 744202-15-1 is a valid CAS Registry Number.

744202-15-1Downstream Products

744202-15-1Relevant articles and documents

Complexes formed from 2,4,6-trimercaptotriazine (H3TMT): Synthesis and structural characterization of [M(PhP(CH2CH 2P(Ph)2)2(HTMT)], M=Ni(II), Pd(II), Pt(II)

Ienco, Andrea,Midollini, Stefano,Orlandini, Annabella,Vacca, Alberto

, p. 2615 - 2623 (2004)

Na3TMT·9H2O (H3TMT=2,4,6- trimercaptotriazine) reacts with M(PPP)Cl2, PPP=PhP(CH 2CH2PPh2)2, M=Ni, Pd, Pt, to give the compounds [M(PPP)(HTMT)]. The nickel and palladium complexes have been characterized by single-crystal X-ray diffraction analysis. PPP is tridentate in both complexes. The nickel complex has an irregular trigonal bipyramidal configuration in which the triazine is bidentate, coordinating through one sulfur and one nitrogen donor atom. The palladium complex has an approximately square planar geometry in which the triazine forms a strong Pd-S bond in the plane and also a very weak Pd-N interaction above the plane. The 31P NMR spectrum of the platinum complex is similar to that of the palladium complex, which is consistent with the Pt complex also having an approximately square-planar structure. Variable temperature NMR spectra show that two conformational isomers of the nickel complex are present in solution at low temperatures, though exchange is fast at room temperature. DFT calculations have confirmed the possible existence of two five-coordinate isomers of comparable stability.

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