744246-08-0

Basic information

• Product Name: 2-thiazolinyl 3,4,6-tri-O-acetyl-2-O-benzyl-1-thio-β-D-glucopyranoside
• Synonyms: 2-thiazolinyl 3,4,6-tri-O-acetyl-2-O-benzyl-1-thio-β-D-glucopyranoside
• CAS NO: 744246-08-0
• Molecular Weight: 497.59
• Mol File: 744246-08-0.mol

Chemical Properties

• CAS DataBase Reference: 2-thiazolinyl 3,4,6-tri-O-acetyl-2-O-benzyl-1-thio-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: 2-thiazolinyl 3,4,6-tri-O-acetyl-2-O-benzyl-1-thio-β-D-glucopyranoside(744246-08-0)
• EPA Substance Registry System: 2-thiazolinyl 3,4,6-tri-O-acetyl-2-O-benzyl-1-thio-β-D-glucopyranoside(744246-08-0)

Safety Data

• Hazardous Substances Data: 744246-08-0(Hazardous Substances Data)

Upstream product

• 29741-69-3 3,4,6-tetra-O-acetyl-2-O-benzyl-α-D-glucopyranosyl bromide 
• 71591-75-8 sodium 2-mercaptothiazolinate 

Downstream Products

• 1256155-24-4 methyl 3-O-(3,4,6-tri-O-acetyl-2-O-benzyl-α-D-glycopyranosyl)-2,4,6-tri-O-benzoyl-α-D-glucopyranoside 
• 744246-30-8 methyl 3,4,6-tri-O-acetyl-2-O-benzyl-α-D-glucopyranosyl-(1->4)-2,3,6-tri-O-benzyl-α-D-glucopyranoside 
• 1372765-78-0 methyl 3,4,6-tri-O-acetyl-2-O-benzyl-β-D-glucopyranosyl-(1->4)-2,3,6-tri-O-benzyl-α-D-glucopyranoside 
• 1256155-25-5 methyl 3-O-(3,4,6-tri-O-acetyl-2-O-benzyl-α-D-glycopyranosyl)-2,4,6-tri-O-benzyl-α-D-glucopyranoside 
• 1256155-27-7 methyl 2-O-(3,4,6-tri-O-acetyl-2-O-benzyl-α-D-glycopyranosyl)-3,4,6-tri-O-benzoyl-α-D-glucopyranoside 
• 1372765-77-9 methyl 3,4,6-tri-O-acetyl-2-O-benzyl-β-D-glucopyranosyl-(1->6)-2,3,4-tri-O-benzoyl-α-D-glucopyranoside 
• 1256155-22-2 methyl 4-O-(3,4,6-tri-O-acetyl-2-O-benzyl-α-D-glycopyranosyl)-2,3,6-tri-O-benzoyl-α-D-glucopyranoside 

Relevant articles and documents

S-thiazolinyl (STaz) glycosides as versatile building blocks for convergent selective, chemoselective, and orthogonal oligosaccharide synthesis

In the aim of developing new procedures for efficient oligosaccharide assembly, a range of 5-thiazolinyl (STaz) glycosides have been synthesized. These novel derivatives were evaluated against a variety of reaction conditions and were shown to be capable of being chemoselectively activated in the armed-disarmed fashion. More over, the S-thiazolinyl moiety exhibited a remarkable propensity for selective activation over other common leaving groups. Conversely, a variety of leaving groups could be selectively activated over the STaz moiety, which, in turn, allowed STaz/S-ethyl and STaz/S-phenyl orthogonal approaches. To demonstrate versatility of novel STaz derivatives, a number of oligosaccharide targets have been synthesized in a convergent selective, orthogonal, and chemoselective fashion.

Potent, versatile, and stable: Thiazolyl thioglycosides as glycosyl donors

Donating with a difference: Thiazolyl (Taz) substituted thioglycosides have been successfully used in the synthesis of both 1,2-trans- and 1,2-cis-glycosides and also have found application in convergent oligosaccharide synthesis. In addition, this study