71591-75-8

Basic information

• Product Name: Sodium 2-thiazoline-2-thiolate
• Synonyms: Sodium 2-thiazoline-2-thiolate
• CAS NO: 71591-75-8
• Molecular Formula: C₃H₄NS₂*Na
• Molecular Weight: 0
• Mol File: 71591-75-8.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Sodium 2-thiazoline-2-thiolate(CAS DataBase Reference)
• NIST Chemistry Reference: Sodium 2-thiazoline-2-thiolate(71591-75-8)
• EPA Substance Registry System: Sodium 2-thiazoline-2-thiolate(71591-75-8)

Safety Data

• Hazardous Substances Data: 71591-75-8(Hazardous Substances Data)

Upstream product

• 96-53-7 2-mercaptothiazoline 

Downstream Products

• 153334-55-5 2-(3-hydroxy-2-pyridyl)-2-thiothiazoline 
• 14125-75-8 2,3,4,6-tetra-O-benzoyl-D-hydroxyglucal 
• 744245-92-9 2-thiazolinyl 2,3,4,6-tetra-O-benzoyl-1-thio-β-D-glucopyranoside 
• 744246-08-0 2-thiazolinyl 3,4,6-tri-O-acetyl-2-O-benzyl-1-thio-β-D-glucopyranoside 
• 1200396-64-0 2-thiazolinyl 2,3,4,-tri-O-benzyl-6-O-(2,2'-bipyridin-6-yl)-1-thio-β-D-glucopyranoside 
• 150501-35-2 dicarbonyl(η1-mercaptothiazolinate)(μ-mercaptothiazolinate){bis(diphenylphosphino)methane}diiridium 
• 150501-38-5 chlorodicarbonyl(μ-mercaptothiazolinate)bis(bis(diphenylphosphino)methane)diiridium 
• 150501-37-4 dicarbonyl(μ-mercaptothiazolinate)bis{bis(diphenylphosphino)methane}dirhodium chloride * CH2Cl2 
• 744246-20-6 C₂₂H₂₇NO₈S₂ 
• 904297-72-9 2-thiazolinyl 2,6-di-O-benzoyl-3,4-O-isopropylidene-1-thio-β-D-galactopyranoside 
• 904297-65-0 2-thiazolinyl 3,4,6-tri-O-acetyl-2-O-benzyl-1-thio-β-D-galactopyranoside 
• 744246-41-1 2-thiazolinyl 2-O-benzyl-4,6-O-benzylidene-1-thio-β-D-glucopyranoside 
• 744246-05-7 2-thiazolinyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-glucopyranoside 

Relevant articles and documents

The synthesis of some binuclear ruthenium(I) complexes bridged by anionic groups. X-ray structures of pyrazolate- and oxypyridinate-bridged complexes

A series of binuclear ruthenium(I) complexes, , have been prepared by two closely related routes.Complexes 2 (XY- = S2NC3H4-) and 3 (XY- = NC5H4O-) have been prepared by the reaction of with sodium 2-mercaptothiazolinate and sodium 2-oxypyridinate, respectively.The related pyrazolate-bridged complex 4 (XY- = N2C3H3-) was prepared by the reaction of sodium pyrazolate with followed by addition of PPh3.The X-ray structures of compounds 3 and 4 have been determined.Compound 3 crystallizes in the triclinic space group P1 with a 14.766(2), b 15.821(2), c 10.745(3) Angstroem, α 98.28(2) deg, β 11.99(2) deg, γ 103.29(1) deg, V 2209.1 Angstroem3, Z = 2.On the basis of 5521 unique observations (NO) and 379 parameters varied (NV) the structure has been refined to R = 0.042 and Rw = 0.054.Compound 4 crystallizes in the orthorombic space group P212121 with a 13.220(2), b 14.864(4), c 21.403(3) Angstroem, V 4200.7 Angstroem3 and Z = 4.This structure has been refined to R = 0.041 and Rw = 0.023 for NO = 3915 and NV = 546.Both structures display the sawhorse arrangement of carbonyl groups and have the phosphine ligands in the axial positions opposite the Ru-Ru binds.For 3 the oxypyridinate groups are bound in a head-to-tail arrangement.The two-atom pyrazolate bridge imparts more strain than the three-atom oxypyridinate bridge and as a result the equatorial planes of the Ru centers are tipped by only 16.2(4) deg in 3 but by 35.4(1) deg in 4.The Ru-Ru distances (2.7108(4) Angstroem (3); 2.732(1) Angstroem (4)) correspond to normal single bonds.