74481-94-0Relevant academic research and scientific papers
(η5-C5H5)(Ph2PCH2CH2PPh2)Ru=CH2+ AsF6-. SPECTRAL CHARACTERIZATION AND MEASUREMENT OF THE BARRIER TO METHYLENE ROTATION
Studabaker, William B.,Brookhart, M.
, p. C39 - C41 (1986)
The electrophilic methylene complex (η5-C5H5)(Ph2PCH2CH2PPh2)Ru=CH2+ (1) has been characterized by 13C and variable-temperature 1H NMR spectroscopy and exhibits a vertical orientation of the methylene group with a barrier for rotation about the ruthenium-carbon double bond of 10.9 kcal/mol.
