74483-09-3

Upstream product

• 78-27-3 1-Ethynylcyclohexan-1-ol 
• 504-02-9 1,3-cylohexanedione 
• 1193-55-1 2-methylcyclohexane-1,3-dione 
• 10575-77-6 1-bromo-3,3-(pentamethylene)-1,2-propadiene 
• 37457-15-1 3-isobutoxy-2-methyl-2-cyclohexen-1-one 

Downstream Products

• 102724-96-9 <2'-(3''-cyano-3''-(trimethylsiloxy)-2''-methylcyclohex-1''-en-1''-yl)ethenylidene>cyclohexane 
• 102724-98-1 (Z)-1-cyclohex-1'-en-1'-yl-2-<3''-cyano-3''-(trimethylsiloxy)-2''-methylcyclohex-1''-yl>ethene 
• 102724-97-0 <2'-(3''-(trimethylsilyloxy)-2''-methylcyclohex-1''-en-1''-yl)ethenylidene>cyclohexane 
• 102725-00-8 (Z)-<2'-(3''-trimethylsilyloxy)-2''-methylcyclohex-1''-en-1''-yl)ethenylidene>cyclohexane 
• 102724-99-2 (Z)-1-cyclohexylidene-2-<3'-(trimethylsiloxy)-2'-methylenecyclohexylidene>ethane 
• 74483-12-8 (Z)-1-(Cyclohex-1'-en-1'-yl)-2-(3-hydroxy-2-methylenecyclohex-1-en-1-yl)ethene 
• 74483-11-7 (Z)-1-Cyclohexylidene-2-(3'-hydroxy-2'-methylenecyclohexylidene)ethane 
• 74483-13-9 (Z)-1-(Cyclohex-1'-en-1'-yl)-2-(2-methyl-3-oxocyclohex-1-en-1-yl)ethene 
• 74483-14-0 cisoid-1,2,4a,4b,5,6,7,8-Octahydro-4a-methyl-4(3H)-phenanthrone 
• 74483-15-1 5',6'-Dihydrospiro-8'(7'H)-one 
• 74483-10-6 <2'-(3-Hydroxy-2-methylcyclohex-1-en-1-yl)ethenylidene>cyclohexane 

Relevant academic research and scientific papers

Studies on Vitamin D (Calciferol) and Its Analogues. 19. Rearrangement of Vinylallenes to 1-Hydroxylated Vitamin D Model Systems Lacking the D Ring and Side Chain

The thermally induced sigmatropic shifts of vinylallenone 7 and vinylallenol 8 were studied.The former (7) rearranges (approximately 100 deg C, 18 h) to previtamin ketone model system 13 in essentially quantitative yield; further thermolysis (approximatel