74483-11-7

Upstream product

• 74483-10-6 <2'-(3-Hydroxy-2-methylcyclohex-1-en-1-yl)ethenylidene>cyclohexane 
• 74483-12-8 (Z)-1-(Cyclohex-1'-en-1'-yl)-2-(3-hydroxy-2-methylenecyclohex-1-en-1-yl)ethene 
• 78-27-3 1-Ethynylcyclohexan-1-ol 
• 10575-77-6 1-bromo-3,3-(pentamethylene)-1,2-propadiene 
• 74483-09-3 <2'-(2-Methyl-3-oxocyclohex-1-en-1-yl)ethenylidene>cyclohexane 
• 504-02-9 1,3-cylohexanedione 
• 37457-15-1 3-isobutoxy-2-methyl-2-cyclohexen-1-one 
• 1193-55-1 2-methylcyclohexane-1,3-dione 
• 193622-63-8 1-(tert-Butyl-dimethyl-silanyloxy)-3-[1-iodo-1-trimethylsilanyl-meth-(Z)-ylidene]-2-methylene-cyclohexane 
• 146334-72-7 3-[1-Iodo-meth-(Z)-ylidene]-2-methylene-cyclohexanol 
• 143660-74-6 ⁽³⁾-tert-butyldimethyl(oct-1-en-7-yn-3-yloxy)silane 
• 193622-64-9 tert-Butyl-{3-[1-iodo-meth-(Z)-ylidene]-2-methylene-cyclohexyloxy}-dimethyl-silane 
• 88924-29-2 tributyl(cyclohexylidenemethyl)stannane 
• 122700-33-8 3-(tert-Butyl-dimethyl-silanyloxy)-8-trimethylsilanyl-oct-1-en-7-yne 

Downstream Products

• 74483-12-8 (Z)-1-(Cyclohex-1'-en-1'-yl)-2-(3-hydroxy-2-methylenecyclohex-1-en-1-yl)ethene 
• 102724-99-2 (Z)-1-cyclohexylidene-2-<3'-(trimethylsiloxy)-2'-methylenecyclohexylidene>ethane 

Relevant academic research and scientific papers

Alkenylzinc-Mediated Approach to the Vitamin D Skeleton. Application to the Synthesis of 6-Methyl Analogs of Vitamin and Previtamin D

Palladium-catalyzed cross-coupling of alkenylzinc reagents, bearing the C,D-ring/side chain portion, and (Z)-1-iodo-1,3-bis-exocyclic dienes (as A-ring precursors), provides a mild, convergent entry to the vitamin D skeleton, that is suitable for the synt

A novel entry to the vitamin D triene system

The application of Negishi's cyclization methodology to the synthesis of (Z)-1-iodo-1,3-bis-exocyclic-dienes from acyclic precursors is described. This kind of compounds can be used for the preparation of conjugated systems such as the triene of vitamin D

Studies on Vitamin D (Calciferol) and Its Analogues. 19. Rearrangement of Vinylallenes to 1-Hydroxylated Vitamin D Model Systems Lacking the D Ring and Side Chain

The thermally induced sigmatropic shifts of vinylallenone 7 and vinylallenol 8 were studied.The former (7) rearranges (approximately 100 deg C, 18 h) to previtamin ketone model system 13 in essentially quantitative yield; further thermolysis (approximatel