74502-32-2

Upstream product

• 278-06-8 tetracyclo-[3.2.0.0.^2,7.0^4,6]heptane 
• 7669-54-7 2-nitrobenzenesulfenyl chloride 
• 64-19-7 acetic acid 
• 121-46-0 bicyclo[2.2.1]hepta-2,5-diene 

Downstream Products

• 87110-34-7 (1R,2S,4S,6R)-5-(2-Nitro-phenylsulfanyl)-tricyclo[2.2.1.0^2,6]heptan-3-one 
• 74456-95-4 3-(2'-nitrophenylthio)-tricyclo<2.2.1.0^2.6>heptane 
• 87110-33-6 (1R,2S,3R,4S,5R,6R)-5-(2-Nitro-phenylsulfanyl)-tricyclo[2.2.1.0^2,6]heptan-3-ol 
• 87110-33-6 (1R,2S,3S,4S,5R,6R)-5-(2-Nitro-phenylsulfanyl)-tricyclo[2.2.1.0^2,6]heptan-3-ol 

Relevant academic research and scientific papers

Electrophilic claevage of cyclopropanes. IV. The reaction of 2-nitrobenzenesulphenyl chloride with tetracyclo2.7.04.6>heptane and acetic acid: the crystal structure of exo-3-(2'-nitrophenylthio)-exo-5-methoxytricyclo<2.2.1.0<

The electrophilic cleavage of a cyclopropane single bond in tetracyclo2.7.04.6>heptane by 2-nitrobenzenesulphenyl chloride in methanol and acetic acid has been studied using both nmr and single crystal X-ray structural determ

Reaction of 2,4-Dinitrobenzenesulfenyl Chloride with Quadricyclene

The treatment of quadricyclene with 2,4-dinitrobenzenesulfenyl chloride has been reinvestigated and chloro adducts 1-A and 2b-A as well as acetates 4a-A, 4b-A, 6, and 7 have been obtained.Establishing 2b-A with endo-chloride led to important conclusion that endo-chloride attack occurs by collapse of ion pair.Monitoring changes in the proportions of acetates, especially with added LiClO4, has allowed conclusions about the degree of development of the carbocation intermediates.These conclusions were proposed on the basis of the previously published ideas of stereocontrol by an ion pair.