7453-04-5Relevant articles and documents
Stereospecific Nickel-Catalyzed Reductive Cross-Coupling of Alkyl Tosylate and Allyl Alcohol Electrophiles
Alexanian, Erik J.,Tercenio, Quentin D.
supporting information, p. 7215 - 7219 (2021/09/22)
The stereospecific cross-coupling of easily accessed electrophiles holds significant promise in the construction of C-C bonds. Herein, we report a nickel-catalyzed reductive coupling of allyl alcohols with chiral, nonracemic alkyl tosylates. This cross-coupling delivers valuable allylation products with high levels of stereospecificity across a range of substrates. The catalytic system consists of a simple nickel salt in conjunction with a commercially available reductant and importantly represents a rare example of a cross-coupling involving the C-O bonds of two electrophiles.
The Conformational Preference of the Diphenylphosphinoyl Group in Cyclohexane
Juaristi, Eusebio,Lopez-Nunez, Norma A.,Glass, Richard S.,Petsom, Amorn,Hutchins, Robert O.,Stercho, Juriy P.
, p. 1357 - 1360 (2007/10/02)
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