74532-23-3Relevant academic research and scientific papers
Synthetic Route to 2-Deoxyaldoses by Fluoride-Catalyzed Solvolysis of Enol-Phosphate Esters
Mitsuo, Naoki,Abe, Yoshihiro,Takizawa, Takeo,Kunieda, Takehisa
, p. 1327 - 1330 (2007/10/02)
1-Alkenyl and phenyl phosphate esters undergo smooth cleavage of the phosphorous-oxygen linkage by fluoride-catalyzed alcoholysis to give aldehydes (ketones) and phenols, respectively.Application of this method provides a new route to 2-deoxyaldosugars from the enol-phosphates derived from vinylene carbonate telomers.Keywords -- vinylene carbonate telomer; 2-deoxyaldose; enol phosphate; cesium fluoride; aryl phosphate
