74536-45-1Relevant academic research and scientific papers
Chemical and Electrochemical Oxidative Dimerization of Carbonyl Compounds by Cerium(IV) Salts. A Comparative Study
Cho, Liu Yao,Romero, Jose Ricardo
, p. 8757 - 8760 (2007/10/02)
β-dicarbonyl and β-cyanocarbonyl compounds were dimerized chemically by CAN or by electrocatalysis using cerous nitrate as mediator.The saturated and unsaturated products of these oxidations are presented.
ELECTROCHEMICAL OXIDATIVE DIMERIZATION OF ACETOACETIC AND BENZOYLACETIC ESTERS IN THE PRESENCE OF METAL HALIDES
Elinson, M.N.,Lizunova, T.L.,Nikishin, G.I.
, p. 2213 - 2216 (2007/10/02)
Acetoacetic and benzoylacetic esters dimerize on electrolysis in the presence of metal halide mediators to form 2,5-dioxohexane-3,4-dicarboxylic and 1,4-dioxo-1,4-diphenylbutane-2,3-dicarboxylic esters in yields up to 90percent.Primarily the meso-form of the dimer is produced (up to 90percent) under optimal conditions (NaI, -20 deg C) in acetone and acetonitrile.Diastereomers of the dimer are produced in comparable amounts in methanol and ethanol.
Hypervalent Iodine Oxidation: α-Functionalization of β-Dicarbonyl Compounds Using Iodosobenzene
Moriarty, Robert, M.,Vaid, Radhe K.,Ravikumar, Vasulinga T.,Vaid, Beena K.,Hopkins, Thomas E.
, p. 1603 - 1608 (2007/10/02)
Hypervalent iodine oxidation of β-diketones and β-ketoesters with iodosobenzene-boron trifluoride etherate in chloroform using appropriate nucleophiles results in α-functionalization.Benzoylacetone on reaction with iodosobenzene or iodosobenzene boron trifluoride-etherate in methanol yields α-methoxyacetophenone (9) and methyl phenylacetate (10).The possible mechanisms for these reactions are discussed.
