74538-22-0

Upstream product

• 563-76-8 α-bromopropionyl bromide 
• 74-89-5 methylamine 

Downstream Products

• 57837-16-8 2-(2,4-Dichloro-6-methyl-phenylamino)-propionic acid methyl ester 
• 57837-17-9 2-(4-Bromo-2-chloro-6-methyl-phenylamino)-propionic acid methyl ester 
• 57837-12-4 2-(2-Chloro-4-iodo-6-methyl-phenylamino)-propionic acid methyl ester 
• 89909-95-5 2-Dimethylamino-propionsaeure-methylamid 
• 19386-68-6 2-(2-Chloro-6-methyl-phenylamino)-N-methyl-propionamide 
• 58006-99-8 3,5-dimethyloxazolidine-2,4-dione 
• 93713-30-5 (R)-N²,N^2'-dimethyl-[1,1'-binaphthalene]-2,2'-diamine 

Relevant academic research and scientific papers

Switchable Smiles Rearrangement for Enantioselective O-Aryl Amination

Asymmetric assembly of atropisomeric anilines from abundant and readily available precursors is one of the most challenging but valuable processes in organic synthesis. The use of highly efficient Smiles rearrangement to accomplish switchable enantioselec

Tetraethylammonium hydrogen carbonate in organic synthesis: Synthesis of oxazolidine-2,4-diones

Oxazolidine-2,4-diones were synthesised by tetraethylammonium hydrogen (TEAHC) promoted carboxylation of secondary carboxamides bearing a leaving group at the α-position. Several oxazolidine-2,4-diones, including clinically used malidone, have been prepared in moderate to excellent yields as a results of a formal proton extraction-carboxylation- intramolecular S(N)2 one-pot sequence.