74635-85-1

Upstream product

• 110612-11-8 (1R,4S,4aR,8aS)-4-(Hydroxymethyl)-3,4a,8,8-tetramethyl-1,4,4a,5,6,7,8,8a-octahydronaphthalen-1-ol 
• 110547-82-5 ((1S,4aS,8aR)-2,5,5,8a-Tetramethyl-4-oxo-1,4,4a,5,6,7,8,8a-octahydronaphthalen-1-yl)methyl acetate 
• 74636-06-9 uvidin A 
• 105479-59-2 (1S,4S,4aS,8aS)-4-Hydroxy-2,5,5,8a-tetramethyl-1,4,4a,5,6,7,8,8a-octahydro-naphthalene-1-carboxylic acid methyl ester 
• 105479-59-2 (1S,4R,4aS,8aS)-4-Hydroxy-2,5,5,8a-tetramethyl-1,4,4a,5,6,7,8,8a-octahydro-naphthalene-1-carboxylic acid methyl ester 
• 105479-58-1 (1aS,3aS,7aS,7bR)-2,3a,7,7-Tetramethyl-1a,3a,4,5,6,7,7a,7b-octahydro-1-oxa-cyclopropa[a]naphthalene-3-carboxylic acid methyl ester 
• 105479-60-5 (1S,4aS,8aS)-2,5,5,8a-Tetramethyl-4-oxo-1,4,4a,5,6,7,8,8a-octahydro-naphthalene-1-carboxylic acid methyl ester 
• 105479-56-9 (1aR,2aS,6aS,7R,7aS)-3,3,6a,7a-Tetramethyl-decahydro-1-oxa-cyclopropa[b]naphthalene-7-carboxylic acid methyl ester 
• 22567-25-5 (3R,4aS,8aS)-3-Hydroxy-2,5,5,8a-tetramethyl-3,4,4a,5,6,7,8,8a-octahydro-naphthalene-1-carboxylic acid methyl ester 
• 22567-24-4 (1R,3R,4aS,8aS)-3-Hydroxy-5,5,8a-trimethyl-2-methylene-decahydro-naphthalene-1-carboxylic acid methyl ester 
• 105479-57-0 (4aS,8aS)-2,5,5,8a-Tetramethyl-4a,5,6,7,8,8a-hexahydro-naphthalene-1-carboxylic acid methyl ester 
• 111319-83-6 methyl bicyclofarnesate 
• 326795-30-6 (1S,3R,4S,4aR,8aS)-4-({[tert-Butyl(dimethyl)silyl]oxy}methyl)-3,4a,8,8-tetramethyldecahydronaphthalene-1,3-diol 
• 326795-31-7 (3R,4S,4aR,8aS)-4-({[tert-Butyl(dimethyl)silyl]oxy}methyl)-3-hydroxy-3,4a,8,8-tetramethyloctahydronaphthalen-1(2H)-one 

Relevant academic research and scientific papers

REARRANGEMENT OF A HINDERED ALLYLIC ALCOHOL DURING VANADIUM-CATALYZED EPOXIDATION. A SHORT SYNTHESIS OF UVIDIN-C.

A study on the hydroxyl-directed epoxidation of allylic alcohols 3b and 3c is provided, leading to a synthesis of uvidin-C (1).

Synthesis of drimanes from (+)-larixol

The selective transformation of the side chain of larixol 1 to a functionalized one-carbon moiety leads to 6,8-diacetoxydrimenal 13, which was converted to the drimanes (-)-albrassitriol (2), (-)-drimenol (3), (-)-uvidin C (4) and (-)-epi-albrassitriol (5).

Synthesis of Natural Uvidin C

The first synthesis of (-)-Uvidin C from (-)-drimenol through the ketol is described.

Fungal Metabolites. Part 5. Uvidins, New Drimane Sesquiterpenes from Lactarius uvidus Fries

Uvidin A (IIa) and uvidin B (IIc) along with (-)-drimenol have been isolated from Lactarius uvidus Fries (Basidiomycetes).The structure and the stereochemistry of the two uvidins have been determined both by spectroscopic data and chemical reactions.Compound (IIa) has been correlated with (+)-drimanol (VIII) by transformations into (VI) and then (VII).Reactions and spectroscopic data are discussed.