74637-19-7Relevant academic research and scientific papers
REACTION OF ENOLATES OF ACYLTRIMETHYLSILANES WITH ALDEHYDES. CANNIZZARO TYPE OXIDATION-REDUCTION REACTION WITH A TRIMETHYLSILYLCARBONYL GROUP
Kuwajima, Isao,Matsumoto, Kazuhisa,Sugahara, Shuichi
, p. 525 - 528 (2007/10/02)
The reaction of an acyltrimethylsilane enolate with 2 eq of an aldehyde gives a 1:2 adduct, while that with the enolate of an α-chloroacyltrimethylsilane affords an α,β-unsaturated aldehyde as a 1:1 adduct accompanied by the carboxylic acid derived from the starting aldehyde.An oxidation-reduction reaction mechanism on the trimethylsilylcarbonyl group has been proposed.
