74670-42-1Relevant articles and documents
Preparation and Some Reactions of Thioacyl Diphenylthiophosphinoyl and Thioacyl Diphenylphosphino Sulfides
Kato, Shinzi,Goto, Masahisa,Hattori, Rikizoh,Nishiwaki, Koh-ichi,Mizuta, Masateru,Ishida, Masaru
, p. 1668 - 1683 (2007/10/02)
The reaction of sodium or caesium dithiocarboxylates with diphenylthiophosphinic and diphenylselenophosphinic chlorides gives purple thioacyl diphenylthiophosphinoyl 5 and dark green thioacyl diphenylselenophosphinoyl sulfides 6, which are useful thioacylating reagents under mild reaction conditions.Thioacyl diphenylphosphino sulfides 22, which can be obtained by the similar method using diphenylphosphinous chlorides, react with methanol to yield the corresponding methyl dithiocarboxylates 15, while the reactions of 22 with N-chlorosuccinimide lead to hitherto unknown N-(thioacetylthio)succinimides 28.
A Convenient Preparation Method of Anhydrous Lithium, Potassium, Rubidium and Cesium Dithiocarboxylates
Kato, Shinzi,Yamada, Shunji,Goto, Hideyuki,Terashima, Kiyomitsu,Mizuta, Masateru,Katada, Tomonori
, p. 458 - 462 (2007/10/02)
It has been found that a series of anhydrous alkali metal dithiocarboxylates are readily obtained in good yields by the reaction of dithio acid with metal hydride (LiH, NaH, KH), n-butyl lithium, or rubidium or cesium acetates, respectively.Their spectral