60410-77-7Relevant articles and documents
New Thioacylating Reagents: 1-Methyl-2-thioacylthiopyridinium Salts
Kato, Shinzi,Masumoto, Hiroki,Ikeda, Shin-ichi,Itoh, Masahiro,Murai, Toshiaki,Ishihara, Hideharu
, p. 67 - 69 (2007/10/02)
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Preparation and Some Reactions of Bis(thioacyl) Sulfides
Kato, Shinzi,Shibahashi, Hiroshi,Katada, Tomonori,Takagi, Takashi,Noda, Ippei,et al.
, p. 1229 - 1244 (2007/10/02)
Reaction of dithioic acids with dicyclohexylcarbodiimide has been found to give the corresponding bis(thioacyl) sulfides 1 in good yield, which are very useful thioacylating reagents under mild reaction conditions.Most of the aromatic thioanhydrides (1, R = aromatic) are fairly stable green crystals at room temperature, but the aliphatic ones (1, R = aliphatic) are unstable purple oils which dimerize at room temperature to give the dithietanes 5.The reactions with nucleophiles are discussed.