74693-77-9Relevant academic research and scientific papers
Organoiron Complexes in Organic Synthesis. Part 5. Spirocyclisation Reactions of Tricarbonylcyclohexadienyliumiron Complexes
Pearson, Anthony J.
, p. 400 - 405 (1980)
Attempted spirocyclisation of tricarbonylmalonate>iron hexafluorophosphate (4) and tricarbonyliron hexafluorophosphate (11) to the desired spirodecane derivatives (5) and (12) failed under a variety of mild conditions.Spirocyclisation of tricarbonyliron hexafluorophosphate (25) occurs smoothly and rapidly at -78 ged C to give the tricarbonylundeca-7,9-diene-1-carboxylate)>iron diastereoisomers (26) and (27).
