Organoiron Complexes in Organic Synthesis. Part 5. Spirocyclisation Reactions of Tricarbonylcyclohexadienyliumiron Complexes

DOI: 10.1039/P19800000400

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 400 - 405 (1980)

Update date:2022-07-30

Topics:: Authors:

Pearson, Anthony J.

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Article abstract of DOI:10.1039/P19800000400

Attempted spirocyclisation of tricarbonylmalonate>iron hexafluorophosphate (4) and tricarbonyliron hexafluorophosphate (11) to the desired spiro<4.5>decane derivatives (5) and (12) failed under a variety of mild conditions.Spirocyclisation of tricarbonyliron hexafluorophosphate (25) occurs smoothly and rapidly at -78 ged C to give the tricarbonyl<η-7-10-(methyl 9-methoxy-2-oxospiro<5.5>undeca-7,9-diene-1-carboxylate)>iron diastereoisomers (26) and (27).

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Organoiron Complexes in Organic Synthesis. Part 5. Spirocyclisation Reactions of Tricarbonylcyclohexadienyliumiron Complexes

DOI: 10.1039/P19800000400

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Article abstract of DOI:10.1039/P19800000400

Full text of DOI:10.1039/P19800000400

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