Organoiron Complexes in Organic Synthesis. Part 5. Spirocyclisation Reactions of Tricarbonylcyclohexadienyliumiron Complexes

DOI: 10.1039/P19800000400

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 400 - 405 (1980)

Update date:2022-07-30

Topics:: Authors:

Pearson, Anthony J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/P19800000400

Attempted spirocyclisation of tricarbonylmalonate>iron hexafluorophosphate (4) and tricarbonyliron hexafluorophosphate (11) to the desired spiro<4.5>decane derivatives (5) and (12) failed under a variety of mild conditions.Spirocyclisation of tricarbonyliron hexafluorophosphate (25) occurs smoothly and rapidly at -78 ged C to give the tricarbonyl<η-7-10-(methyl 9-methoxy-2-oxospiro<5.5>undeca-7,9-diene-1-carboxylate)>iron diastereoisomers (26) and (27).

Full text of DOI:10.1039/P19800000400

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:2-[1-(4-Methoxycarbonyl-butyl)-4-oxo-cyclohex-2-enyl]-malonic acid dimethyl ester

Cas No:74693-77-9

R&D Labs maybe for 74693-77-9

Zhejiang Linhai Xinhua Chemicals Factory

Contact:0086-13661858911

Address:Xunqiao Development Zone, Linhai, Zhejiang, China
miao tie sheng

Contact:0311-13263231263

Address:jian hua street,Shijiazhuang City, China
Beijing Mesochem Technology Co.,LTD

website:http://www.mesochem.com

Contact:0086-10-57862036

Address:2301, Floor 23, Building 9 Lippo Plaza, Yard 8 Ronghua Middle Road, ETDZ, Beijing, China
enantiotech corporation ltd

Contact:+86-0760-85282375

Address:zhongjing road,zhongshan torch hi-tech industrial development zone
TIANJIN NORTH JINHENG CHEMICAL PLANT.

Contact:0086-22-59952083

Address:DongShigu Country In JiXian TianJin China

Relevant to this article

A GENERAL SYNTHETIC METHOD FOR ORSELLINIC ACID MOIETY OF MACROLIDES BY THE PALLADIUM-CATALYZED CARBONYLATION OF ARYL IODIDE AND ITS APPLICATION TO ZEARALENONE SYNTHESIS

Doi:10.1246/cl.1980.369
(1980)
1,3-Dipolar Character of Six-membered Aromatic Rings. Part 51. Cycloadditions of 1-(β-Benzoylvinyl)-3-oxidopyridiniums and Subsequent Transformations

Doi:10.1039/P19800000362
(1980)
Doi:10.1021/ja01290a502
(1937)
Doi:10.1002/apmc.1978.050730109
(1978)
Benzene Alkylation with Cycloolefins under the Action of [Et₃NH]⁺[Al₂Cl₇]^? Ionic Liquid

Doi:10.1134/S107036321911001X
(2019)
HYDROGEN TRANSFER FROM TERTIARY AMINES TO TRIFLUOROACETIC ANHYDRIDE

Doi:10.1016/S0040-4039(00)78830-7
(1980)

Article Doi

Organoiron Complexes in Organic Synthesis. Part 5. Spirocyclisation Reactions of Tricarbonylcyclohexadienyliumiron Complexes

DOI: 10.1039/P19800000400

Source and publish data:

Authors:

Article abstract of DOI:10.1039/P19800000400

Full text of DOI:10.1039/P19800000400

Products guided by the article

R&D Labs maybe for 74693-77-9

Relevant to this article

Hot Product