Organoiron Complexes in Organic Synthesis. Part 5. Spirocyclisation Reactions of Tricarbonylcyclohexadienyliumiron Complexes

DOI: 10.1039/P19800000400

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 400 - 405 (1980)

Update date:2022-07-30

Topics:: Authors:

Pearson, Anthony J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/P19800000400

Attempted spirocyclisation of tricarbonylmalonate>iron hexafluorophosphate (4) and tricarbonyliron hexafluorophosphate (11) to the desired spiro<4.5>decane derivatives (5) and (12) failed under a variety of mild conditions.Spirocyclisation of tricarbonyliron hexafluorophosphate (25) occurs smoothly and rapidly at -78 ged C to give the tricarbonyl<η-7-10-(methyl 9-methoxy-2-oxospiro<5.5>undeca-7,9-diene-1-carboxylate)>iron diastereoisomers (26) and (27).

Full text of DOI:10.1039/P19800000400

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:2-[1-(4-Methoxycarbonyl-butyl)-4-oxo-cyclohex-2-enyl]-malonic acid dimethyl ester

Cas No:74693-77-9

R&D Labs maybe for 74693-77-9

Tianjin Ingenochem Technology Co.,Ltd

Contact:+86-22-23677060

Address:Hitech Green Industry Park K2-9-602, Nankai district
Joyochem Co., Ltd.

website:https://sdjingyuan.lookchem.com/

Contact:86-531-82687998

Address:Factory Building 11, Jinan Comprehensive free trade zone, Shandong, China
NEW LUNA PHARM CO.,LTD

Contact:Type:+86-0311-85637430

Address:#23.NANSAN ROAD,FENGTAI AREA,BEIJING CITY.
Disynthesis Chemical Technology Co. Ltd.

Contact:+86-571-88194596

Address:Dengyun road 380, Gongshu district, Hangzhou city, China
Jiangsu Haian Petro chemical Plant

Contact:+86-513-88902723

Address:99, Changjiang West Road, Haian County, Jiangsu

Relevant to this article

A GENERAL SYNTHETIC METHOD FOR ORSELLINIC ACID MOIETY OF MACROLIDES BY THE PALLADIUM-CATALYZED CARBONYLATION OF ARYL IODIDE AND ITS APPLICATION TO ZEARALENONE SYNTHESIS

Doi:10.1246/cl.1980.369
(1980)
1,3-Dipolar Character of Six-membered Aromatic Rings. Part 51. Cycloadditions of 1-(β-Benzoylvinyl)-3-oxidopyridiniums and Subsequent Transformations

Doi:10.1039/P19800000362
(1980)
Doi:10.1021/ja01290a502
(1937)
Doi:10.1002/apmc.1978.050730109
(1978)
Benzene Alkylation with Cycloolefins under the Action of [Et₃NH]⁺[Al₂Cl₇]^? Ionic Liquid

Doi:10.1134/S107036321911001X
(2019)
HYDROGEN TRANSFER FROM TERTIARY AMINES TO TRIFLUOROACETIC ANHYDRIDE

Doi:10.1016/S0040-4039(00)78830-7
(1980)

Article Doi

Organoiron Complexes in Organic Synthesis. Part 5. Spirocyclisation Reactions of Tricarbonylcyclohexadienyliumiron Complexes

DOI: 10.1039/P19800000400

Source and publish data:

Authors:

Article abstract of DOI:10.1039/P19800000400

Full text of DOI:10.1039/P19800000400

Products guided by the article

R&D Labs maybe for 74693-77-9

Relevant to this article

Hot Product