74694-99-8Relevant academic research and scientific papers
The Thermal Elimination of Iodine from Some Substituted α-Iodonaphthalenes: a Structural Study
Cameron, Donald W.,Feutrill, Geoffrey I.,Pannan, Linda J. H.,Raston, Colin L.,Skelton, Brian W.,White, Allan H.
, p. 610 - 627 (2007/10/02)
Brief heating of a number of methyl 8-iodo-5,7-dimethoxy-2-naphthoate derivatives with a variety of added hydroxy-, methoxy-, or acetoxy-substituents in the 4- and 6-positions has been found to result in facile elimination of iodine in certain compounds but not others; subsequent examination of other aspects of the chemistry of the system have suggested this to be a solid state effect.Single crystal X-ray structure determinations have been carried out on a representative selection of compounds, suggesting that in those examples where elimination has been found to occur, intimate charge-transfers interactions between the conjugated systems of adjacent molecules arising from the nature of the crystal packing are responsible; in those compounds which do not eliminate iodine, similar interactions may also be found but are associated with substituent out-of-plane steric interactions which hinder relative movement of the naphthalene moieties in the lattice.
Synthesis of a Natural Hexachloro Dinaphthofuran Quinone
Cameron, Donald W.,Feutrill, Geoffrey I.,Pannan, Linda J. H.
, p. 2531 - 2541 (2007/10/02)
1,3,6,8,11,13-Hexachloro-4,10-dihydroxy-5,9-dihydrodinaphthofuran-5,9-dione (1), a pigment isolated from soils and the only natural example of this ring system, has been synthesized for the first time.
