74708-35-3

Basic information

• Product Name: DL-Tetra-O-acetyl-(1,3,6/2)-6-azido-4-(hydroxymethyl)-4-cyclohexene-1,2,3-triol
• Synonyms: DL-Tetra-O-acetyl-(1,3,6/2)-6-azido-4-(hydroxymethyl)-4-cyclohexene-1,2,3-triol
• CAS NO: 74708-35-3
• Molecular Weight: 369.331
• Mol File: 74708-35-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: DL-Tetra-O-acetyl-(1,3,6/2)-6-azido-4-(hydroxymethyl)-4-cyclohexene-1,2,3-triol(CAS DataBase Reference)
• NIST Chemistry Reference: DL-Tetra-O-acetyl-(1,3,6/2)-6-azido-4-(hydroxymethyl)-4-cyclohexene-1,2,3-triol(74708-35-3)
• EPA Substance Registry System: DL-Tetra-O-acetyl-(1,3,6/2)-6-azido-4-(hydroxymethyl)-4-cyclohexene-1,2,3-triol(74708-35-3)

Safety Data

• Hazardous Substances Data: 74708-35-3(Hazardous Substances Data)

Upstream product

• 77144-73-1 5,7-O-benzylidene derivative of DL-3,4-di-O-acetyl-1,2-anhydro-(1,2,4,6/3,5)-1,2,3,4,5-pentahydroxy-6-hydroxymethylcyclohexane 
• 77144-65-1 DL-O-triacetyl-(1,3/2,4)-4-<(benzoyloxy)methyl>-5-cyclohexene-1,2,3-triol 
• 77144-72-0 (1SR,3SR,6RS,8SR,9SR,10SR)-9,10-diacetoxy-3-phenyl-2,4-dioxabicyclo[4.4.0]dec-7-ene 
• 70838-35-6 DL-(1,3/2,4,6)-1,2,3-tri-O-acetyl-4-bromo-6-bromomethyl-1,2,3-cyclohexanetriol 
• 77144-67-3 DL-(1,3/2,4)-4-(hydroxymethyl)-5-cyclohexene-1,2,3-triol 
• 74024-01-4 DL-(1,3/2)-1,2,3-tri-O-acetyl-4-methylene-5-cyclohexene-1,2,3-triol 
• 81692-16-2 DL-tetra-O-acetyl-(1,3/2,4)-4-chloro-4-C-hydroxymethyl-5-cyclohexene-1,2,3-triol 
• 127-08-2 potassium acetate 
• 74615-52-4 DL-tri-O-acetyl-(1,3,6/2)-6-bromo-4-bromomethyl-4-cyclohexene-1,2,3-triol 
• 74615-52-4 DL-tri-O-acetyl-(1,3/2,6)-6-bromo-4-bromomethyl-4-cyclohexene-1,2,3-triol 
• 84851-94-5 DL-Di-O-acetyl-1,7-O-benzylidene-5-O-(methylsulfonyl)-(1,3,4/2,5,6)-4-azido-6-(hydroxymethyl)-1,2,3,5-cyclohexanetetrol 
• 84851-93-4 DL-2,3,-Di-O-acetyl-1,7-O-benzylidene-(1,3,4/2,5,6)-4-azido-6-(hydroxymethyl)-1,2,3,5-cyclohexanetetrol 
• 86861-73-6 Acetic acid (1R,4S,5S,6S)-4,5-diacetoxy-1-chloro-6-hydroxy-cyclohex-2-enylmethyl ester 
• 81692-14-0 DL-2,3,4-tri-O-acetyl-1,7-anhydro-(1,2,4/3)-1-C-hydroxymethyl-5-cyclohexene-1,2,3,4-tetrol 

Downstream Products

• 81692-22-0 Acetic acid (4aS,5R,6S,7S,8S,8aR)-8-acetoxy-5-hydroxy-2-phenyl-6-((3aR,4R,9aS,9bR)-2,2,8,8-tetramethyl-4,6,9a,9b-tetrahydro-3aH-[1,3]dioxolo[4',5':3,4]benzo[1,2-d][1,3]dioxin-4-ylamino)-hexahydro-benzo[1,3]dioxin-7-yl ester 
• 81692-21-9 Acetic acid (4aR,5S,6R,7S,8S,8aR)-8-acetoxy-6-hydroxy-2-phenyl-5-((3aR,4R,9aS,9bR)-2,2,8,8-tetramethyl-4,6,9a,9b-tetrahydro-3aH-[1,3]dioxolo[4',5':3,4]benzo[1,2-d][1,3]dioxin-4-ylamino)-hexahydro-benzo[1,3]dioxin-7-yl ester 
• 81692-22-0 DL-N-<(1SR)-4,7:5,6-di-O-isopropylidene-4,5,6-trihydroxy-3-(hydroxymethyl)-2-cyclohexenyl>-(1SR)-2,3-di-O-acetyl-4,7-O-benzylidene-(1,2,4/3,5,6)-2,3,4,6-tetrahydroxy-5-(hydroxymethyl)cyclohexylamine 
• 81692-21-9 N-<(1SR)-4,7:5,6-di-O-isopropylidene-4,5,6-trihydroxy-3-(hydroxymethyl)-2-cyclohexenyl>-(1SR)-3,4-di-O-acetyl-5,7-O-benzylidene-(1,3,5/2,4,6)-2,3,4,5-tetrahydroxy-6-(hydroxymethyl)cyclohexylamine 
• 74645-52-6 valienamine 

Relevant articles and documents

Synthetic studies on the validamycins. IV. Synthesis of DL- valienamine and related branched-chain unsaturated aminocyclitols

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SYNTHESIS OF DL-VALIDOXYLAMINE B

DL-Validoxylamine B was first synthesized by the reaction of DL-4,7:5,6-di-O-isopropylidene-(1,4,6/5)-4,5,6-trihydroxy-3-hydroxy-methyl-2-cyclohexenylamine with DL-3,4-di-O-acetyl-1,2-anhydro-5,7-O-benzylidene-(1,2,4,6/3,5)-6-hydroxymethyl-1,2,3,4,5-cyclo