77144-67-3

Upstream product

• 70838-35-6 DL-(1,3/2,4,6)-1,2,3-tri-O-acetyl-4-bromo-6-bromomethyl-1,2,3-cyclohexanetriol 
• 77144-65-1 DL-O-triacetyl-(1,3/2,4)-4-<(benzoyloxy)methyl>-5-cyclohexene-1,2,3-triol 

Downstream Products

• 77144-72-0 (1SR,3SR,6RS,8SR,9SR,10SR)-9,10-diacetoxy-3-phenyl-2,4-dioxabicyclo[4.4.0]dec-7-ene 
• 126661-83-4 (1R^*,6S^*)-cyclophellitol 
• 77144-73-1 5,7-O-benzylidene derivative of DL-3,4-di-O-acetyl-1,2-anhydro-(1,2,4,6/3,5)-1,2,3,4,5-pentahydroxy-6-hydroxymethylcyclohexane 
• 84851-94-5 DL-Di-O-acetyl-1,7-O-benzylidene-5-O-(methylsulfonyl)-(1,3,4/2,5,6)-4-azido-6-(hydroxymethyl)-1,2,3,5-cyclohexanetetrol 
• 77144-76-4 DL-Tri-O-acetyl-1,7-O-benzylidene-(1,3,5/2,4,6)-4-azido-6-(hydroxymethyl)-1,2,3,4-cyclohexanetetrol 
• 77144-64-0 DL-Pentaacetylhydroxyvalidamine 
• 77144-74-2 DL-Tri-O-acetyl-1,7-O-benzylidene-(1,3,4/2,5,6)-4-azido-6-(hydroxymethyl)-1,2,3,5-cyclohexanetetrol 

Relevant academic research and scientific papers

Stereocontrolled synthesis of ara-type cyclohexenyl nucleosides

A highly stereocontrolled synthesis of a new class of carbocyclic nucleosides, ara-type cyclohexenyl nucleosides, was developed. The key intermediate (±)-9 was obtained after a series of transformations starting from easily available endo-bicyclo carboxyl

Synthetic studies on the validamycins. IX. Synthesis of some racemic isomers of validoxylamine A

Two racemic isomers of validoxylamine A have been synthesized by use of coupling reactions of the protected DL-validamine and the allyl bromides, the precursors of the unsaturated branched-chain cyclitol moiety. The racemix diasteromers thus formed can be

Synthetic Studies on the Validamycins. 5. Synthesis of DL-Hydroxyvalidamine and DL-Valienamine

A first synthesis of the peracetyl racemate (25) of hydroxyvalidamine (3), one of the degradation products of antibiotic validamycin B (1), is reported.The present result fully confirmed the proposed structure of 3.The sequence of reactions involves stere

SYNTHESIS OF HEXA-N,O-ACETYL-DL-HYDROXYVALIDAMINE

DL-(1,3,4/2,5,6)-4-amino-6-hydroxymethyl-1,2,3,5-cyclohexanetetrol (DL-hydroxyvalidamine) was first synthesized as the peracetate, which confirmed the proposed structure of the branched-chain aminocyclitol derived by hydrogenolysis of antibiotic validamyc