7471-86-5

Basic information

• Product Name: Benzenecarboximidic acid methyl ester
• Synonyms: Benzenecarboximidic acid methyl ester;Benzenecarboximidic Acid Methyl Ester(WXC04573)
• CAS NO: 7471-86-5
• Molecular Formula: C₈H₉NO
• Molecular Weight: 135.16316
• Mol File: 7471-86-5.mol
• Article Data: 24

Chemical Properties

• Boiling Point: 171.1 °C at 760 mmHg
• Flash Point: 57.3 °C
• Appearance: /
• Density: 1 g/cm³
• Vapor Pressure: 1.89mmHg at 25°C
• Refractive Index: 1.503
• CAS DataBase Reference: Benzenecarboximidic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenecarboximidic acid methyl ester(7471-86-5)
• EPA Substance Registry System: Benzenecarboximidic acid methyl ester(7471-86-5)

Safety Data

• Hazardous Substances Data: 7471-86-5(Hazardous Substances Data)

Usage

General Description

Benzenecarboximidic acid methyl ester, also known as methyl benzimidate, is a chemical compound with the molecular formula C9H9NO2. It is commonly used as an intermediate in the synthesis of pharmaceuticals and agricultural chemicals. Benzenecarboximidic acid methyl ester has been identified as a potential mutagen and is known to have toxic effects on aquatic organisms. It is important to handle this chemical with care and follow proper safety procedures when working with it. Additionally, as with any chemical substance, it is essential to be aware of its potential hazards and to use appropriate protective measures to minimize risk.

InChI:InChI=1/C8H9NO/c1-10-8(9)7-5-3-2-4-6-7/h2-6,9H,1H3/b9-8-

Upstream product

• 60-29-7 diethyl ether 
• 87457-81-6 benzamide; silver-salt 
• 74-88-4 methyl iodide 
• 55-21-0 benzamide 
• 77-78-1 dimethyl sulfate 
• 873-67-6 benzonitrile oxide 
• 698-16-8 benzohydroximoyl chloride 
• 932-90-1 Benzaldoxime 
• 127700-29-2 α-azidobenzyl methyl ether 
• 5873-90-5 methyl benzimidate hydrochloride 
• 100-47-0 benzonitrile 
• 78488-67-2 methyl N-(phenyldichloroseleno)benzimidate 
• 67-56-1 methanol 

Downstream Products

• 101934-61-6 N-(Methoxyphenylmethylen)carbamidsaeure-ethylester 
• 5221-67-0 5-methyl-2-phenyloxazole 
• 827-43-0 4-methyl-2-phenyl-1H-imidazole 
• 73289-49-3 N-acetyl methyl benzimidate 
• 55-21-0 benzamide 
• 877-39-4 4-methyl-2-phenyloxazole 
• 716-79-0 2-phenyl-1H-benzoimidazole 
• 1022-45-3 2-phenyl-4(3H)-quinazolinone 
• 1022-45-3 2-phenyl-1,4-dihydroquinazolin-4-one 
• 712-66-3 methyl N-propionyl benzimidate 
• 52714-07-5 2'-methyl-5'-phenyl-2',4'-dihydro-2H-spiro[benzo[1,3,2]dioxaphosphole-2,3'-[1,2,4,3]triazaphosphole] 
• 52714-06-4 1,7,7,8,8-pentamethyl-3-phenyl-6,9-dioxa-1,2,4-triaza-5λ⁵-phospha-spiro[4.4]non-2-ene 
• 32990-31-1 2,3-dimethyl-5-phenyl-3,4-dihydro-2H-[1,2,4,3]triazaphosphole 
• 52713-98-1 1-Methyl-5-phenyl-1,2,4,3-triazaphosphole 

Relevant articles and documents

Regioselective synthesis of a new [1,2,3]-triazoles directly from imidates

A one pot synthetic approach to the novel [1,2,3]-triazoles system, by 1,3-dipolar cycloaddition of 2-diazopropane to the imidates 2, is described. The structures of the obtained adducts have been assigned by means of spectroscopic measurements.

Synthesis of Highly Fused Pyrano[2,3- b]pyridines via Rh(III)-Catalyzed C-H Activation and Intramolecular Cascade Annulation under Room Temperature

A facile access to the polycyclic-fused pyrano[2,3-b]pyridines has been established under room temperature via Rh(III)-catalyzed C-H bond activation and intramolecular cascade annulation. This strategy features high efficiency, unique versatility, and gen

Flow rhodaelectro-catalyzed alkyne annulations by versatile C-H Activation: Mechanistic support for rhodium(III/IV)

A flow-metallaelectro-catalyzed C-H activation was realized in terms of robust rhodaelectro-catalyzed alkyne annulations. To this end, a modular electro-flow cell with a porous graphite felt anode was designed to ensure efficient turnover. Thereby, a variety of C-H/N-H functionalizations proved amenable for alkyne annulations with high levels of regioselectivity and functional group tolerance, viable in both an inter- or intramolecular manner. The electro-flow C-H activation allowed easy scale up, while in-operando kinetic analysis was accomplished by online flow-NMR spectroscopy. Mechanistic studies suggest an oxidatively induced reductive elimination pathway on rhodium(III) in an electrocatalytic regime.