74733-96-3

Basic information

• Product Name: 4-acetoxy-2-(p-nitrophenyl)-4,5,6,7-terahydro-2H-benzo<1,2,3>triazole
• Synonyms: 4-acetoxy-2-(p-nitrophenyl)-4,5,6,7-terahydro-2H-benzo<1,2,3>triazole
• CAS NO: 74733-96-3
• Molecular Weight: 302.29
• Mol File: 74733-96-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 4-acetoxy-2-(p-nitrophenyl)-4,5,6,7-terahydro-2H-benzo<1,2,3>triazole(CAS DataBase Reference)
• NIST Chemistry Reference: 4-acetoxy-2-(p-nitrophenyl)-4,5,6,7-terahydro-2H-benzo<1,2,3>triazole(74733-96-3)
• EPA Substance Registry System: 4-acetoxy-2-(p-nitrophenyl)-4,5,6,7-terahydro-2H-benzo<1,2,3>triazole(74733-96-3)

Safety Data

• Hazardous Substances Data: 74733-96-3(Hazardous Substances Data)

Upstream product

• 108-24-7 acetic anhydride 
• 203380-92-1 1,2-bis(p-nitrophenylazo)cyclohexene 
• 74733-85-0 cyclohexane-1,2-dione-bis-(4-nitro-phenylhydrazone) 
• 100-16-3 4-nitrophenylhydrazone 
• 765-87-7 cyclohexane-1,2-dione 
• 74733-85-0 C₁₈H₁₈N₆O₄ 

Relevant articles and documents

Regioselective Intramolecular Rearrangements in 1,2-Bis(areneazo)cycloalkenes via Triazolium Imide 1,3-Dipoles: Examples of a New Fischer Indole-type Rearrangement. Azolium 1,3-Dipoles. Part 2.

1,2-Bis(areneazo)cycloalkenes (2) (6 carbons and higher) when heated or treated with acid rearrange to hydro derivatives of fused 2,4-diarylcyclopolyenotriazoles (3).The rearrangement, which was regioselective and intramolecular, occured through a 1,2,3-triazolium imide 1,3-dipole form of the substrates (2).Synthesis, structural effects, a variable-temperature 270 MHz n.m.r. search for intermediates, and some kinetic studies are reported.The reaction is a new variation of the Fischer indole reaction.

Isomerism and Lead(IV) Acetate Oxidation Reactions of p-Substituted Phenylosazones of Some Substituted Glyoxals and 1,2-Diketones. Reactions of Metallic Acetates with Nitrogen Compounds. Part 5.

The structures of the bis-(p-nitrophenyl)hydrazones and some bis-(p-bromophenyl)hydrazones of glyoxal, methylglyoxal, phenylglyoxal, butane-2,3-dione, benzil, and cyclohexane-1,2-dione were examined by i.r., 1H n.m.r., and 13C n.m.r. spectroscopy.Generally the E,E forms of the osazones were obtained from direct synthesis except for the bis-(p-nitrophenyl)hydrazone of cyclohexane-1,2-dione and phenylglyoxal and the bis-(p-bromophenyl)hydrazones of phenylglyoxal, which were obtained as the E,Z-chelate forms.Unstable yellow crystalline forms of the bis-(p-nitrophenyl)hydrazones of glyoxal, butane-2,3-dione, and benzil containing two molecules of hexamethylphosphoramide (HMPA) of crystallisation, which may contain the E,Z-isomers, were isolated from HMPA solutions.Lead tetra-acetate oxidation of a range of E,E-osazones gave dehydrogenations to 1,2-bisazoethylenes.Similar oxidations of E,Z-osazones gave mainly 2-aryl-1,2,3-trizole type products (osotriazoles) along with lower yields of azoethylenes.Oxidation of cyclohexane-1,2-dione bis-(p-nitrophenyl)hydrazone gave a mixture of osotriazoles containing an acethoxy- or p-nitroacetanilido-group at the 3-position of the cyclohexyl ring.