74739-75-6Relevant academic research and scientific papers
A New, Convenient Synthesis of N2-Aryl-N1-alkylformamidines and N2-Aryl-N1,N1-dialkylformamidines
Cereda, Enzo,Bellora, Elio,Donetti, Arturo
, p. 288 - 291 (2007/10/02)
N2-Aryl-N1-alkylformamidines are conveniently and rapidly prepared by the reaction of an aromatic amine with ethyl N-cyanoformamidate to give the N2-aryl-N1-cyanoformamidine.Addition of this intermediate to an e
STEREOSPECIFIC FORMATION OF AMIDINES BY 1,1-ADDITION OF AMINES TO ISOCYANIDES
Hegarty, Anthony F.,Chandler, Anne
, p. 885 - 888 (2007/10/02)
Addition of secondary amines to isonitriles in the presence of AgCl at low temperature gives isolable but thermodynamically unstable Z-amidines; only the more stable 6E undergoes ring expansion to the imidazoline 7.
