74755-82-1Relevant academic research and scientific papers
STEREOSPECIFIC FORMATION OF AMIDINES BY 1,1-ADDITION OF AMINES TO ISOCYANIDES
Hegarty, Anthony F.,Chandler, Anne
, p. 885 - 888 (1980)
Addition of secondary amines to isonitriles in the presence of AgCl at low temperature gives isolable but thermodynamically unstable Z-amidines; only the more stable 6E undergoes ring expansion to the imidazoline 7.
