STEREOSPECIFIC FORMATION OF AMIDINES BY 1,1-ADDITION OF AMINES TO ISOCYANIDES

DOI: 10.1016/S0040-4039(00)71534-6

Source and publish data:

Tetrahedron Letters p. 885 - 888 (1980)

Update date:2022-08-05

Topics:

Authors:

Hegarty, Anthony F.

Chandler, Anne

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)71534-6

Addition of secondary amines to isonitriles in the presence of AgCl at low temperature gives isolable but thermodynamically unstable Z-amidines; only the more stable 6E undergoes ring expansion to the imidazoline 7.

Full text of DOI:10.1016/S0040-4039(00)71534-6

Products guided by the article

Product name:(4-Nitro-phenyl)-[1-piperidin-1-yl-meth-(Z)-ylidene]-amine

Cas No:74755-82-1

R&D Labs maybe for 74755-82-1

Shanghai Xinda Pharmaceuticals Co., Ltd.

Contact:86-21-33692333-8008

Address:999 Linxian Road, Jinshan Industrial Park, Shanghai, China
Liaoyang Xinyou Chemical Products Co.,Ltd.

Contact:+86-419-5165433 13604191870

Address:Huishang Road6-1, Hongwei District, Liaoyang, Liaoning, China
Qingdao Kylin Trading Co., Ltd.

Contact:0086-532-68979884/58972912/68972263/65/88171519

Address:Room 2308,A building International Trade Center No.230 Changjiang Middle Road of Qingdao Economic Development Zone,Shandong,China.
Onlychem (Jinan)Biotech Co.,Ltd

Contact:86-531-83175885

Address:No. 44, Honglou South Road, Jinan,China
Suzhou Credit International Trading Co., Ltd

Contact:+86-512-65398039

Address:Qingdeng, Hightech. District, Suzhou

Relevant to this article

Conformationally constrained 1,3-diamino ketones: A series of potent inhibitors of the cysteine protease cathepsin K [3]

Doi:10.1021/jm980295f
(1998)
Alkylation of 5'-guanylic acid by reductively activated mitomycin C

Doi:10.1248/cpb.28.1961
(1980)
Cytochalasin support studies. Chiral and stereochemical control via an intramolecular Diels-Alder reaction of a (Z)-diene

Doi:10.1021/ja00538a068
(1980)
A shortcut to the smaller fragment of pamamycin-607

Doi:10.1016/S0040-4039(01)01044-9
(2001)
Highly selective synthesis of 2-substituted-5-hydroxy-6-oxo-1,6- dihydropyrimidine-4-carboxylic acid derivatives using a novel protected dihydroxyfumarate

Doi:10.1016/j.tetlet.2004.06.028
(2004)
Reaction of [PPN][Re(CO)₅] with [Mn(CO)₅(C ₂H₄)][BF₄], a rapid two-electron, ethylene transfer reaction, PPN=bis(triphenylphosphine)nitrogen(1+)

Doi:10.1016/S0020-1693(02)00793-4
(2002)

Article Doi