STEREOSPECIFIC FORMATION OF AMIDINES BY 1,1-ADDITION OF AMINES TO ISOCYANIDES

DOI: 10.1016/S0040-4039(00)71534-6

Source and publish data:

Tetrahedron Letters p. 885 - 888 (1980)

Update date:2022-08-05

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Authors:

Hegarty, Anthony F.

Chandler, Anne

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Article abstract of DOI:10.1016/S0040-4039(00)71534-6

Addition of secondary amines to isonitriles in the presence of AgCl at low temperature gives isolable but thermodynamically unstable Z-amidines; only the more stable 6E undergoes ring expansion to the imidazoline 7.

Full text of DOI:10.1016/S0040-4039(00)71534-6

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