74758-55-7Relevant academic research and scientific papers
N-donor-stabilized Pd(II) species supported by sulphonamide-azo ligands: Ligand architecture, solvent co-ligands, C–C coupling
Oloyede, Hammed Olawale,Orighomisan Woods, Joseph Anthony,G?rls, Helmar,Plass, Winfried,Eseola, Abiodun Omokehinde
, (2019/09/10)
In this report, a series of synthetically affordable phosphine-free ligands (L1 – L4) of the form RSO2–NH–Ph–N[dbnd]N–Ph–NH–SO2R were prepared and examined as organic ligands for stabilizing palladium active centers; R = methyl, tolyl or triiso-propylphenyl. Palladium complexes, which were obtained in varying coordination environments as well as with varying complementary co-ligands (water, acetonitrile or pyridine), have been subjected to Suzuki and Heck coupling experiments in order to study molecular level ligand effects on preferred catalyst settings. The appreciable coupling activities for Suzuki and Heck coupling with functional group tolerance were recorded for palladium species generated from the chelate ligands. Results show that, despite the tridentate chelation characteristics of these azo-benzene ligands, the introduction of bulky units at the sulfonyl groups enabled generation of active palladium species with high turnover frequencies; e.g. 5040 h?1 (84% yield) within 5 min at 0.2 mol % loading of Pd.L2.py in only water as solvent. A correlation between catalytic efficiencies and the bulkiness of the coordinated co-ligand was obtained. However, while Suzuki coupling activity increased with increase in co-ligand sizes of the preformed complexes (i.e. water acetonitrile pyridine), the pyridyl co-ligand turned out to be very unfavourable for Heck coupling where the acetonitrile-complemented complexes possessed the higher activities. Therefore, it could be concluded that the best catalyst setting for Suzuki coupling may not be the best for Heck reaction.
Fluorescent dyestuffs
-
, (2008/06/13)
Fluorescent dyestuffs of the formula STR1 wherein: R1 and R2 independently of one another represent hydrogen, a salt-forming cation, an alkyl radical with 1 to 8 carbon atoms or an aralkyl radical which is optionally substituted by non-chromophoric groups, R2 to R5 independently of one another represent hydrogen, alkyl, trifluoromethyl, alkoxy, aralkoxy, alkenyloxy, halogen or the carboxyl, cyano, alkylsulphonyl, arylsulphonyl, carboxamide or sulphonamide group or a carboxylic acid ester group, m and n independently of one another denote 0, 1 or 2 and the sum of m+n must be at least 2, and o, p, q and r independently of one another represent 0, 1 or 2. processes for their preparation, their use for whitening organic materials and a process for the production of a coherent laser emission using the fluorescent dyestuffs according to formula I.
