74789-57-4Relevant academic research and scientific papers
Silicon-Promoted Carbon-Carbon Bond Formation between Ketones and Allyl- or Vinylsilanes Catalyzed by Manganese(IV) Dioxide
Hwu, Jih Ru,Chen, Buh-Luen,Shiao, Shui-Sheng
, p. 2448 - 2455 (1995)
The influence of silicon on the carbon-carbon bond formation was investigated by use of various silylalkenes to react with ketones.Treatment of an allylsilane (CH2=CHCH2SiMemPhn; m + n = 3) with various ketones (20 equiv) in the presence of MnO2 (2.0 equi
