Silicon-Promoted Carbon-Carbon Bond Formation between Ketones and Allyl- or Vinylsilanes Catalyzed by Manganese(IV) Dioxide

DOI: 10.1021/jo00113a027

Source and publish data:

Journal of Organic Chemistry p. 2448 - 2455 (1995)

Update date:2022-09-26

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Authors:

Hwu, Jih Ru

Chen, Buh-Luen

Shiao, Shui-Sheng

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Article abstract of DOI:10.1021/jo00113a027

The influence of silicon on the carbon-carbon bond formation was investigated by use of various silylalkenes to react with ketones.Treatment of an allylsilane (CH2=CHCH2SiMemPhn; m + n = 3) with various ketones (20 equiv) in the presence of MnO2 (2.0 equi

Full text of DOI:10.1021/jo00113a027

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