748133-89-3Relevant academic research and scientific papers
Synthesis, crystal structure and spectroscopic studies of a cobalt(III) Schiff base complex and its use as a heterogeneous catalyst for the oxidation reaction under mild condition
Islam, S. Manirul,Roy, Anupam Singha,Dalapati, Sasanka,Saha, Rajat,Mondal, Paramita,Ghosh, Kajari,Chatterjee, Saptarshi,Sarkar, Keka,Guchhait, Nikhil,Mitra, Partho
, p. 94 - 103 (2013/11/06)
A new Schiff base oriented Co(III) complex, (CoL)Cl4H2O (L = Schiff base), has been synthesized by careful design of the Schiff base ligand thorough oxidation of Co(II) to Co(III) during the reaction process. The complex has been characterized by single-crystal X-ray structure analysis and various spectral analyses. Structure analysis reveals that this monomeric complex crystallizes in triclinic P-1 space group. Supramolecular hydrogen bonding interactions among the guest water molecules and counter anion chloride leads to the formation of 1D water-chloride chain. A polymer anchored heterogeneous cobalt complex has been synthesized, characterized by various physicochemical techniques and successfully used for the oxidation of alkenes and sulfides using H2O2 as oxygen source. The influence of the various reaction parameters has been studied. The heterogeneous cobalt complex can be reused seven times without any significant loss in its catalytic activity.
Mono and bimetallic CoIII Schiff base complexes: Coordination induced ligand imidazolidine ring cleavage and stabilization
Paul, Supriti,Wong, Wing-Tak,Ray, Debashis
experimental part, p. 160 - 167 (2011/07/31)
2-(2′-Hydroxyphenyl) imidazoline ring grafted dinucleating diimine-diamine-tris-phenol ligand (H3aeas) has been obtained from a two-step reaction of 2-hydroxy acetophenone, N,N′-bis-(2-aminoethyl) ethylenediamine and 2-hydroxy benzaldehyde. Rea
