74867-43-9

Basic information

• Product Name: (R)-(-)-1-Decen-3-ol
• Synonyms: (R)-(-)-1-Decen-3-ol
• CAS NO: 74867-43-9
• Molecular Weight: 156.268
• Mol File: 74867-43-9.mol
• Article Data: 25

Chemical Properties

• CAS DataBase Reference: (R)-(-)-1-Decen-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-(-)-1-Decen-3-ol(74867-43-9)
• EPA Substance Registry System: (R)-(-)-1-Decen-3-ol(74867-43-9)

Safety Data

• Hazardous Substances Data: 74867-43-9(Hazardous Substances Data)

Upstream product

• 13125-66-1 n-heptylmagnesium bromide 
• 107-02-8 acrolein 
• 872-05-9 1-Decene 
• 124-13-0 Octanal 
• 1826-67-1 vinyl magnesium bromide 
• 74824-53-6 dec-1-yn-3-ol 
• 84988-53-4 (E)-2-decenyl chloride 
• 86297-50-9 2-Trimethylsilanyl-dec-1-en-3-ol 
• 629-04-9 1-Bromoheptane 
• 3536-96-7 vinylmagnesium chloride 
• 113680-06-1 dec-2-enyltrimethylsilane 
• 1187817-22-6 (Z)-2-(dec-2-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 1730-25-2 allylmagnesium bromide 

Downstream Products

• 56991-23-2 dec-1-en-3-yl acetate 
• 2497-23-6 (E)-2-decenyl acetate 
• 2497-23-6 (Z)-dec-2-en-1-yl acetate 
• 116138-77-3 3-((E)-Dec-2-enyl)-2-hydroxy-5-methoxy-[1,4]benzoquinone 
• 629-23-2 tetradecan-3-one 
• 928-80-3 decan-3-one 
• 122016-58-4 1-Methyl-4-(1-vinyl-octyloxymethanesulfonyl)-benzene 
• 818-23-5 8-Pentadecanon 
• 112466-92-9 6-Methyl-tetradecan-7-one 
• 112466-96-3 4-Pentyl-decan-3-one 
• 693-23-2 1,12-dodecanedioic acid 
• 55928-67-1 (E)-dodec-4-enoic acid 

Relevant articles and documents

The effect of encapsulated Zn-POM on the catalytic activity of MIL-101 in the oxidation of alkenes with hydrogen peroxide

Zinc monosubstituted Keggin heteropolyanion [PZnMo2W 9O39]5- was electrostatically bound to nanocages of MIL-101 polymer matrix. The Zn-POM@MIL-101 catalyst was characterized by XRD, N2 adsorption, atomic absorption (AAS), and FT-IR spectroscopic methods. The catalytic activity of the new composite material, Zn-POM@MIL-101, was assessed in the oxidation of alkenes using aqueous hydrogen peroxide as oxidant. Zn-POM@MIL-101/H2O2 catalytic system demonstrated good catalytic activity in the oxidation reactions. Zn-POM@MIL-101 was reusable for three catalytic cycles. While the MIL-101 matrix is an active catalyst in these oxidation reactions, the presence of Zn-POM significantly changed the selectivity and reaction times. Copyright

Lewis Base/Br?nsted Acid Co-Catalyzed Asymmetric Thiolation of Alkenes with Acid-Controlled Divergent Regioselectivity

A divergent strategy for the facile preparation of various enantioenriched phenylthio-substituted lactones was developed based on Lewis base/Br?nsted acid co-catalyzed thiolation of homoallylic acids. The acid-controlled regiodivergent cyclization (6-endo vs. 5-exo) and acid-mediated stereoselective rearrangement of phenylthio-substituted lactones were explored. Experimental and computational studies were performed to clarify the origins of the regioselectivity and enantioselectivity. The calculation results suggest that C?O and C?S bond formation might occur simultaneously, without formation of a commonly supposed catalyst-coordinated thiiranium ion intermediate and the potential π–π stacking between substrate and SPh as an important factor in the enantio-determining step. Finally, this methodology was applied in the rapid syntheses of the bioactive natural products (+)-ricciocarpin A and (R)-dodecan-4-olide.

An organocatalyzed Stetter reaction as a bio-inspired tool for the synthesis of nucleic acid-based bioconjugates

An N-Heterocyclic Carbene (NHC) catalyzed biomimetic Stetter reaction was applied for the first time as a bioconjugation reaction to sensitive nucleoside-type biomolecules to provide original pyrrole linked nucleolipids. A versatile approach allowed the functionalization of thymidine at the three reactive positions (O-5′, O-3′ and N-3) providing a structural diversity oriented synthesis. This strategy was applied to the synthesis of an original glyconucleolipid amphiphile in the hope that the pyrrole aromatic moiety would induce additional self-assembling properties.