74915-05-2

Basic information

• Product Name: [C₅H₅Fe(CO)2Cl₂(P(C₆H₅)2CH₂)2FeC₅H₅]
• CAS NO: 74915-05-2
• Molecular Weight: 767.234
• Mol File: 74915-05-2.mol

Chemical Properties

• CAS DataBase Reference: [C₅H₅Fe(CO)2Cl₂(P(C₆H₅)2CH₂)2FeC₅H₅](CAS DataBase Reference)
• NIST Chemistry Reference: [C₅H₅Fe(CO)2Cl₂(P(C₆H₅)2CH₂)2FeC₅H₅](74915-05-2)
• EPA Substance Registry System: [C₅H₅Fe(CO)2Cl₂(P(C₆H₅)2CH₂)2FeC₅H₅](74915-05-2)

Safety Data

• Hazardous Substances Data: 74915-05-2(Hazardous Substances Data)

Upstream product

• 74915-04-1 C₅H₅FeCOHP(C₆H₅)2CH₂CH₂P(C₆H₅)2FeCOHC₅H₅ 

Relevant articles and documents

REACTIVITY MODES OF BRIDGED BIMETALLIC 5-C5H5)Fe(CO)>2-μ-dppe WITH ELECTROPHILES. PREPARATION AND REACTIONS OF BIMETALLIC HYDRIDE COMPLEXES

The complex 5-C5H5)Fe(CO)>2-μ-dppe (dppe = ethane-1,2-bisdiphenylphosphide) (I) reacts with electrophiles through a μ-CO and forms Lewis acid O-adducts with alkylating reagents (giving cationic μ2-alkoxycarbyne compounds) or with alkylaluminum compounds.Treatment of I with acid affords a stable μ2-hydride salt (IV), 2(μ2-H)(μ2-dppe)+, which serves as an intermediate in the stepwise hydrogenation (reversibly) of I to a bridged bimetallic dihydride, 2-μ2-dppe.This dihydride serves as a hydride donor, regenerating IV, towards Ph3C+ o r CpFe(CO)2(η2-CH2=CH2)+ hydride acceptors.The necessity of the μ2-dppe as a mechanical linkage in facilitating some bimetallic reactions is also established.