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CAS

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74915-04-1

C5H5FeCOHP(C6H5)2CH2CH2P(C6H5)2FeCOHC5H5 is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 74915-04-1 Structure

  • Basic information

    1. Product Name: C5H5FeCOHP(C6H5)2CH2CH2P(C6H5)2FeCOHC5H5
    2. Synonyms: C5H5FeCOHP(C6H5)2CH2CH2P(C6H5)2FeCOHC5H5
    3. CAS NO:74915-04-1
    4. Molecular Formula:
    5. Molecular Weight: 698.344
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 74915-04-1.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: C5H5FeCOHP(C6H5)2CH2CH2P(C6H5)2FeCOHC5H5(CAS DataBase Reference)
    10. NIST Chemistry Reference: C5H5FeCOHP(C6H5)2CH2CH2P(C6H5)2FeCOHC5H5(74915-04-1)
    11. EPA Substance Registry System: C5H5FeCOHP(C6H5)2CH2CH2P(C6H5)2FeCOHC5H5(74915-04-1)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 74915-04-1(Hazardous Substances Data)

74915-04-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 74915-04-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,4,9,1 and 5 respectively; the second part has 2 digits, 0 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 74915-04:
(7*7)+(6*4)+(5*9)+(4*1)+(3*5)+(2*0)+(1*4)=141
141 % 10 = 1
So 74915-04-1 is a valid CAS Registry Number.

74915-04-1Relevant articles and documents

HYDRIDE REDUCTION OF THE CATION 5-C5H5)Fe(Ph2PCH2CH2PPh2)CO>PF6; FORMATION OF (η5-C5H5)FeH(CO)(Ph2PCH2CH2PPh2) AND ELIMINATION OF H2 FROM 5-C5H5)FeH(CO)>2(Ph2PCH2CH2PPh2)

Davies, Stephen G.,Hibberd, John,Simpson, Stephen J.,Watts, Oliver

, p. C31 - C33 (1983)

(η5C5H5)FeH(CO)(Ph2PCH2CH2PPh2), formed in the LiAlH4 reduction of the cation of 5-C5H5)Fe(Ph2PCH2CH2PPh2)CO>PF6, can be converted into 5-C5H5)FeH(CO)>2(Ph2PCH2CH2PPh2), which undergoes thermal and photochemical elim

HYDRIDE REDUCTION OF THE CATION 5-C5H5)Fe(Ph2CH2CH2PPh2)CO>PF6; FORMATION OF (η5-C5H5)FeH(CO)(Ph2CH2CH2PPh2) AND ELIMINATION OF H2 FROM 5-C5H5)FeH(CO)>2(Ph2PCH2CH2PPh2)

Davies, Stephen G.,Hibberd, John,Simpson, Stephen J.,Watts, Oliver

, p. C7 - C8 (2007/10/02)

(η5-C5H5)FeH(CO)(Ph2PCH2CH2PPh2), formed in the LiAlH4 reduction of the cation of 5C5H5)Fe(Ph2PCH2CH2PPh2)CO>PF6, can be converted into 5-C5H5)FeH(CO)>2(Ph2PCH2CH2PPh2), which undergoes thermal and photochemical elim

REACTIVITY MODES OF BRIDGED BIMETALLIC 5-C5H5)Fe(CO)>2-μ-dppe WITH ELECTROPHILES. PREPARATION AND REACTIONS OF BIMETALLIC HYDRIDE COMPLEXES

LaCroce, S. J.,Menard, K. P.,Cutler, A. R.

, p. C79 - C83 (2007/10/02)

The complex 5-C5H5)Fe(CO)>2-μ-dppe (dppe = ethane-1,2-bisdiphenylphosphide) (I) reacts with electrophiles through a μ-CO and forms Lewis acid O-adducts with alkylating reagents (giving cationic μ2-alkoxycarbyne compounds) or with alkylaluminum compounds.Treatment of I with acid affords a stable μ2-hydride salt (IV), 2(μ2-H)(μ2-dppe)+, which serves as an intermediate in the stepwise hydrogenation (reversibly) of I to a bridged bimetallic dihydride, 2-μ2-dppe.This dihydride serves as a hydride donor, regenerating IV, towards Ph3C+ o r CpFe(CO)2(η2-CH2=CH2)+ hydride acceptors.The necessity of the μ2-dppe as a mechanical linkage in facilitating some bimetallic reactions is also established.

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