749181-36-0Relevant academic research and scientific papers
Unsymmetrical platinum(II) complexes with diphosphine ligands
Irisli, Sevil,Sarikahya, Fadime,Sarikahya, Yueksel
, p. 431 - 440 (1997)
In this study, unsymmetrical dipositive platinum(II) complexes of the general formula [Pt(L-L)(L′-L′)]Br2, where L-L and L′-L′ = dppm (Ph2PCH2PPh2), dppe (Ph2P(CH2)2PPh2) or dppp (Ph2P(CH2)3PPh2) have been synthesized and characterized by 31P{1H} NMR, IR, UV-Vis, elemental analyses and conductance data. Chlorine analogs of these complexes have also been prepared in the NMR tube and their 31P(1H) NMR spectra were recorded. In a similar manner, [PtBr2(dcpe)] (dcpe = Cy2P(CH2)2PCy2; Cy = cyclohexyl (C6H11)) has been treated with dppm and dppe to form [Pt(dcpe)(dppm)]Br2 and [Pt(dcpe)(dppe)]Br2, respectively.
MIXED LIGAND COMPLEXES OF PLATINUM(0) CONTAINING DIPHOSPHINES
Clark, Howard C.,Kapoor, Pramesh N.,McMahon, Ian J.
, p. 107 - 116 (2007/10/02)
The reaction of PtCl2L (L = diphosphine) with the appropriate diphosphine L' in ethanol followed by reduction with aqueous sodium borohydride leads to either disproportionation to give mixtures of the bis(diphosphine) complexes PtL2 and PtL'2 or to the fo
