7492-90-2

Usage

Uses

Used in Pharmaceutical Industry:
(S)-(+)-1-BROMO-4-METHYLHEXANE is used as a reactant for the synthesis of various pharmaceuticals. Its reactivity allows for the creation of a wide range of compounds with potential medicinal properties.
Used in Chemical Industry:
(S)-(+)-1-BROMO-4-METHYLHEXANE is used as a solvent in various chemical reactions and industrial processes. Its ability to dissolve a variety of substances makes it a valuable component in the production of specialized chemicals.
Used in Organic Synthesis:
(S)-(+)-1-BROMO-4-METHYLHEXANE is used as a building block in organic synthesis, enabling the creation of complex molecules with specific properties and applications.

Upstream product

• 186581-53-3 diazomethane 
• 1730-89-8 (S)-4-methylhexanoic acid 
• 1767-46-0 (S)-4-methyl-1-hexanol 
• 17043-81-1 (R)-(-)-4-Methyl-Δ^2,3-hexadiensaeure-methylester 
• 22299-70-3 (S)-(+)-1-bromo-3-methylpentane 
• 201230-82-2 carbon monoxide 
• 7492-89-9 (+)-Tris-<(2S)-1,2-dimethyl-butyloxy>-methan 

Downstream Products

• 1767-46-0 (S)-4-methyl-1-hexanol 

Relevant academic research and scientific papers

Selective Aliphatic C-H Oxidation

A composition including a complex of a metal, a tetradentate ligand, at least one ancillary ligand, and a counterion may be used for selective sp3 C—H bond oxidation. The tetradentate ligand may include a N-heterocyclic-N,N′-bis(pyridyl)-ethane-1,2-diamine group or a N,N′-bis(heterocyclic)-N,N′-bis(pyridyl)-ethane-1,2-diamine group. The composition can be used in combination with H2O2 to effect highly selective oxidations of unactivated sp3 C—H bonds over a broad range of substrates. The site of oxidation can be predicted, based on the electronic and/or steric environment of the C—H bond. In addition, the oxidation reaction does not require the presence of directing groups in the substrate.

Volatile lactones - (5S,S)-5-methyl-3-(methylalkyl)furan-2(5H)-ones - Identified in the submerged cultivation of Streptomyces avermitilis

Six new compounds have been identified in the volatile fractions produced during the submerged cultivation of Streptomyces avermitilis. By recording the GC/MS, GC/FTIR, CD, 1H and 13C NMR data and by performing chemical degradation experiments, these compounds were determined to be (5S,S)-5-methyl-3-(methylalkyl)furan-2(5H)-ones. Herein, the existence of volatile lactones with an anteiso structure of the side-chain is thus documented for the first time. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.