749248-30-4Relevant academic research and scientific papers
New synthetic routes to allylic germatranes
Faller, Jack W.,Kultyshev, Roman G.,Parr, Jonathan
, p. 2565 - 2570 (2004)
Two complementary routes allow control of regiochemistry and stereochemistry in the synthesis of allylic germatranes. The first method utilizes a transmetallation reaction between germanium(IV) chloride and the corresponding allylic tributylstannanes. The second route is via a palladium-catalyzed hydrogermylation of conjugated dienes by germatrane, N(CH 2 3 GeH, which gives predominantly Z products.
