2-cyclohexen-1-yl germanium trichloride

Base Information

• Chemical Name: 2-cyclohexen-1-yl germanium trichloride
• CAS No.: 749248-30-4
• Molecular Formula: C₆H₉Cl₃Ge
• Molecular Weight: 260.086
• Mol file: 749248-30-4.mol

Synonyms:

Chemical Property of 2-cyclohexen-1-yl germanium trichloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-cyclohexen-1-yl germanium trichloride

There total 1 articles about 2-cyclohexen-1-yl germanium trichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

germaniumtetrachloride (10038-98-9) + tributyl(cyclohex-2-en-1-yl)stannane (112520-99-7,1177092-71-5) → 2-cyclohexen-1-yl germanium trichloride (749248-30-4)

Guidance literature:

In neat (no solvent); using Schlenk techniques; addn. of GeCl4 to Young's flask containing a stirring bar and 2-cyclohexen-1-yl tributylstannane; sealing under vac.,stirring at room temp. for 2o h; distn. (110°C);

DOI:10.1016/j.jorganchem.2004.05.011

Reference yield: 73.0%

triethanolamine (102-71-6,64114-46-1) + ethanol (64-17-5) + 2-cyclohexen-1-yl germanium trichloride (749248-30-4) → [(2-cyclohexen-1-yl)Ge((OCH2CH2)3N)] (749248-34-8)

Guidance literature:

With triethylamine; In toluene; byproducts: NHEt3Cl; addn. of EtOH and Et3N to soln. of Cl3GeC6H9 in MePh in Schlenk flask under N2 at -78°C; warming to room temp. for 40 min; filtration, washing with MePh; transferring of washings and filtrate to N(CH2CH2OH)3; heating at 9O°C for 6 h; cooling, removal of volatiles; washing with pentane; dissolving in CH2Cl2; filtration, washing with CH2Cl2, evapn. of combined filtrate and washings to dryness; elem. anal.;

DOI:10.1016/j.jorganchem.2004.05.011

upstream raw materials:

germaniumtetrachloride

tributyl(cyclohex-2-en-1-yl)stannane

Downstream raw materials:

[(2-cyclohexen-1-yl)Ge((OCH₂CH₂)3N)]