7493-63-2

Basic information

• Product Name: ALLYL ANTHRANILATE
• Synonyms: ALLYL ANTHRANILATE;FEMA 2020;2-amino-benzoicaci2-propenylester;Allyl 2-aminobenzoate;Anthranilic acid, allyl ester;ALLYL ANTHRANILATE 98+%;Benzoicacid2-amino-2-propenylester;2-Aminobenzoic acid allyl ester
• CAS NO: 7493-63-2
• Molecular Formula: C₁₀H₁₁NO₂
• Molecular Weight: 177.2
• EINECS: 231-331-0
• Product Categories: A-B;Alphabetical Listings;Flavors and Fragrances;Aromatics, Miscellaneous Reagents
• Mol File: 7493-63-2.mol
• Article Data: 7

Chemical Properties

• Melting Point: 224-228 °C(lit.)
• Boiling Point: 105 °C2 mm Hg(lit.)
• Flash Point: 110 °C
• Appearance: Clear golden liquid
• Density: 1.118 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.0011mmHg at 25°C
• Refractive Index: n20/D 1.574(lit.)
• CAS DataBase Reference: ALLYL ANTHRANILATE(CAS DataBase Reference)
• NIST Chemistry Reference: ALLYL ANTHRANILATE(7493-63-2)
• EPA Substance Registry System: ALLYL ANTHRANILATE(7493-63-2)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• Hazardous Substances Data: 7493-63-2(Hazardous Substances Data)

Usage

Description

Allyl Anthranilate is a clear golden liquid with a green leaf-wine odor. It is a synthetic flavoring agent and a flavor enhancer, used in the synthesis of diazabicyclo-heptanone compounds that mimic β-lactam antibiotics.

Uses

Used in Pharmaceutical Industry:
Allyl Anthranilate is used as a synthetic flavoring agent for the synthesis of diazabicyclo-heptanone compounds, which are structurally similar to β-lactam antibiotics. This application aids in the development of new antimicrobial agents.
Used in Food and Beverage Industry:
Allyl Anthranilate is used as a flavor enhancer and flavoring agent, imparting a wine note to various food and beverage products. It is commonly used in beverages and candy at a concentration of 1-2 ppm.
Chemical Properties:
Allyl Anthranilate is stable but may cause discoloration. It should be stored in glass or tin containers to maintain its quality and properties.

As a flavor ingredient

Identification ▼▲ CAS.No.:? 7493-63-2? FL.No.:? 9.719 FEMA.No.:? 2020 NAS.No.:? 2020 CoE.No.:? 254 EINECS.No.:? 231-331-0? JECFA.No.:? 20 　 　 ? Description: Allyl anthranilate is used as a flavor enhancer and flavoring agent. ? Regulatory Status: CoE: n/a FDA: 21 CFR 172.515 FDA (other): n/a JECFA: ADI: Acceptable. No safety concern at current levels of intake when used as a flavoring agent. (1996). Reported uses (ppm): (FEMA, 1994) ▼▲ Food Category? Usual? Max.? Alcoholic beverages? 1.25 2.5 Baked goods? 0.75 1.5 Frozen dairy? 0.3 1 Gelatins, puddings? 2 2 Nonalcoholic beverages? 0.88 1.64 Soft candy? 0.91 2.04 ? Natural occurrence: Not reported found in nature.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

The unsaturated aliphatic hydrocarbons are generally much more reactive than the alkanes, which are saturated aliphatic hydrocarbons. Strong oxidizers may react vigorously with them. Reducing agents can react exothermically to release gaseous hydrogen. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

Health Hazard

ACUTE/CHRONIC HAZARDS: Toxic; fire hazard.

Fire Hazard

ALLYL ANTHRANILATE is probably combustible.

InChI:InChI=1/C10H11NO2/c1-2-7-13-10(12)8-5-3-4-6-9(8)11/h2-6H,1,7,11H2

Upstream product

• 107616-19-3 2-propenyl o-nitrobenzoate 
• 118-48-9 isatoic anhydride 
• 107-18-6 allyl alcohol 
• 552-16-9 ortho-nitrobenzoic acid 
• 118-92-3 anthranilic acid 
• 106-95-6 allyl bromide 

Downstream Products

• 67836-81-1 2-(3,4-Dimethoxy-benzoylamino)-benzoic acid allyl ester 
• 188578-83-8 (2S,4R)-2-(2-Allyloxycarbonyl-phenylcarbamoyl)-4-hydroxy-pyrrolidine-1-carboxylic acid allyl ester 
• 848187-11-1 2-{[3-(2,6-Dichloro-phenyl)-5-methyl-isoxazole-4-carbonyl]-amino }-benzoic acid 
• 1214267-23-8 allyl 2-[(3-allyloxybenzoyl)amino] benzoate 
• 1214267-20-5 allyl 2-([2-allyloxyphenyl]acetyl)amino benzoate 
• 1214267-19-2 allyl 2-[(2-allyloxybenzoyl)amino] benzoate 
• 1214267-21-6 allyl 2-[3-({2-methyl}allyloxyphenyl)propanoyl]amino benzoate 
• 101320-93-8 allyl-2-iodobenzoate 
• 180335-22-2 C₁₆H₁₅N₃O₂ 
• 188578-86-1 (1S,4S)-5-(2-Allyloxycarbonyl-phenyl)-6-oxo-2,5-diaza-bicyclo[2.2.1]heptane-2-carboxylic acid allyl ester 
• 188578-89-4 2-(2-Carboxyphenyl)-2,5-diazabicyclo[2.2.1]heptan-3-one 
• 848187-10-0 2-{[3-(2,6-Dichloro-phenyl)-5-methyl-isoxazole-4-carbonyl]-amino}-benzoic acid allyl ester 

Relevant articles and documents

FUNCTIONAL SKIN COATING POLYMER

Film-forming polymers that contain covalently-attached or non-covalently bound light-filtering, e.g., UV-absorbing, compounds and their use as a skin-protectant coating, such as a sunscreen, are disclosed.

Ketone precursors for organoleptic compounds

The invention discloses ketones of formula I: wherein, Y is an optionally substituted alkyl, cycloalkyl, or cycloalkylalkyl, wherein each alkyl group is straight or branched and each alkyl and cycloalkyl group is saturated or unsaturated; R1is hydrogen or a C1-6alkyl group that is substituted, saturated or unsaturated, straight or branched; A is a chromophoric substituted aromatic ring or ring system; n is an integer; and with the proviso that formula I is not 2-ethoxy-1-phenyl-ethanone. These compositions are useful for the delivery of organoleptic compounds, especially of flavors, fragrances, masking agents and antimicrobial compounds.

Carbapenem antibiotic compounds

A carbapenem compound of the formula (I) STR1 wherein: R1 is 1-hydroxyethyl, 1-fluoroethyl or hydroxymethyl; R2 is hydrogen or C1-4 alkyl; R3 is hydrogen or C1-4 alkyl; R4 is hydroxy or carboxy; and the phenyl ring is optionally further substituted by one or two substituents selected from halo, cyano, C1-4 alkyl, nitro, hydroxy, carboxy, C1-4 alkoxy, trifluoromethyl, C1-4 alkoxycarbonyl, carbamoyl, C1-4 alkylcarbamoyl, di-C1-4 alkylcarbamoyl, amino, C1-4 alkylamino, di-C1-4 alkylamino sulphonic acid, C1-4 alkylS(O)n --(wherein n is 0-2), N-C1-4 alkanesulphonamido, C1-4 alkanoylamino and C1-4 alkanoyl(N-C1-4 alkyl)amino: provided that the phenyl ring is substituted by at least one carboxy; or a pharmaceutically acceptable salt or in vivo hydrolysable ester thereof.