74945-91-8Relevant academic research and scientific papers
TRANSITION METAL ALLYLS IV. THE (η3-ALLYL)2M COMPLEXES OF NICKEL, PALLADIUM AND PLATINUM: REACTION WITH TERTIARY PHOSPHINES
Henc, B.,Jolly, P.W.,Salz, R.,Stobbe, S.,Wilke, G.,et al.
, p. 449 - 476 (1980)
A series of 1:1 adducts have been prepared by treating the bis-η3-allyl complexes of nickel, palladium and platinum with tertiary phosphines.Investigations of their structure in solution as well as in the crystal have shown that both 18-electron (η3-allyl)2M-L complexes as well as 16-electron (η1-allyl)-(η3-allyl)M-L complexes may be formed.
