TRANSITION METAL ALLYLS IV. THE (η3-ALLYL)2M COMPLEXES OF NICKEL, PALLADIUM AND PLATINUM: REACTION WITH TERTIARY PHOSPHINES

DOI: 10.1016/S0022-328X(00)81073-6

Source and publish data:

Journal of Organometallic Chemistry p. 449 - 476 (1980)

Update date:2022-08-05

Topics:

Authors:

Henc, B.

Jolly, P.W.

Salz, R.

Stobbe, S.

Wilke, G.

et al. et al.

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Article abstract of DOI:10.1016/S0022-328X(00)81073-6

A series of 1:1 adducts have been prepared by treating the bis-η³-allyl complexes of nickel, palladium and platinum with tertiary phosphines.Investigations of their structure in solution as well as in the crystal have shown that both 18-electron (η³-allyl)2M-L complexes as well as 16-electron (η¹-allyl)-(η³-allyl)M-L complexes may be formed.

Full text of DOI:10.1016/S0022-328X(00)81073-6

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