74966-71-5

Basic information

• Product Name: Benzene, (2,2-diiodo-1,1-dimethoxyethyl)-
• CAS NO: 74966-71-5
• Molecular Formula: C10H12I2O2
• Molecular Weight: 418.013
• Mol File: 74966-71-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzene, (2,2-diiodo-1,1-dimethoxyethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (2,2-diiodo-1,1-dimethoxyethyl)-(74966-71-5)
• EPA Substance Registry System: Benzene, (2,2-diiodo-1,1-dimethoxyethyl)-(74966-71-5)

Safety Data

• Hazardous Substances Data: 74966-71-5(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 536-74-3 phenylacetylene 

Downstream Products

• 4636-16-2 iodoacetophenone 
• 74966-68-0 2,2-diiodo-1-phenylethan-1-one 

Relevant articles and documents

Iron(III) catalyzed halo-functionalization of alkynes

Abstract Aromatic and aliphatic alkynes can be halo-functionalized to α,α-dihalodimethyl ketals catalyzed by FeCl3 in excellent yields. MeOH is used as a nucleophilic solvent and N-halosuccinimide as the halogen source for this efficient transformation. The resulting α,α-dibromodimethyl ketals can be converted to the corresponding α,α-dibromoketones by treatment with 8% FeCl3 in silica gel.

Facile formations of ketals of α, α-dihaloacetophenones

Ketals of α,α-dihaloacetophenones are prepared in high yields from phenylethyne and N-halosuccinimide with catalytic quantities of p-toluenesulfonic acid.