74971-23-6Relevant academic research and scientific papers
Alxylations of α-methyl substituted β-diketones throught their Cu(II) complexes. Preparation of sterically congested β-diketones
Lloris, Maria E.,Marquet, Jorge,Moreno-Manas, Marcial
, p. 7489 - 7492 (2007/10/02)
The copper(II) complexes of 3-methylpentane-2,4-dione and 2-methyl-1-phenylbutane-1,3-dione are good substrates for C-alkylation with several alkyl bromides including 1-bromoadamantane and 9-bromofluorene. Sterically congested β-diketones have been prepared.
Regio- and Stereoselective 1,2 Wagner-Meerwein Shifts during Trifluoroacetic Acid Catalyzed Isomerization of Unsymmetrically Substituted Tricyclo2,4>heptanes
Gree, Rene,Park, Hokoon,Paquette, Leo A.
, p. 4397 - 4403 (2007/10/02)
The regioselectivity and stereoselectivity which materialize upon trifluoroacetic acid promoted isomerization of variously substituted tricyclo2,4>heptanes have been experimentally determined.The highly strained hydrocarbon substrates h
